The variation of Verdet's constant with temperature has been
determined for carbon bisulphide and water by Rodger and Watson (_loc.
cit._). They find if R_t, R0 are the values of Verdet's constant at
t°C and 0°C. respectively, then for carbon bisulphide R_t = R0 (1 -
.0016961), and for water R_t = R0 (1 - .0000305t - .00000305t²).
For the magnetic metals Kundt found that the rotation did not increase
so rapidly as the magnetic force, but that as this force was increased
the rotation reached a maximum value. This suggests that the rotation
is proportional to the intensity of magnetization, and not to the
magnetic force.
The amount of rotation in a given field depends greatly upon the wave
length of the light; the shorter the wave length the greater the
rotation, the rotation varying a little more rapidly than the inverse
square of the wave length. Verdet[11] has compared in the cases of
carbon bisulphide and creosote the rotation given by the formula
c² / di \
[theta] = mc[gamma] --------- ( c - [lamda] --------- )
[lambda]² \ d[lambda]/
with those actually observed; in this formula [theta] is the angular
rotation of the plane of polarization, m a constant depending on the
medium, [lambda] the wave length of the light in air, and i its index
of refraction in the medium. Verdet found that, though the agreement
is fair, the differences are greater than can be explained by errors
of experiment.
Verdet[12] has shown that the rotation of a salt solution is the sum of
the rotations due to the salt and the solvent; thus, by mixing a salt
which produces negative rotation with water which produces positive
rotation, it is possible to get a solution which does not exhibit any
rotation. Such solutions are not in general magnetically neutral. By
mixing diamagnetic and paramagnetic substances we can get magnetically
neutral solutions, which, however, produce a finite rotation of the
plane of polarization. The relation of the magnetic rotation to chemical
constitution has been studied in great detail by Perkin,[13]
Wachsmuth,[14] Jahn[15] and Schönrock.[16]
Public-domain text, read in full here on John Shaqi.
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