A more extended study of the behaviour of the spectroscopic lines has
afforded examples in which the effects produced by a magnet are more
complicated than those we have described, indeed the simple cases are
much less numerous than the more complex. Thus Preston[47] and Cornu[48]
have shown that under the action of a transverse magnetic field one of
the D lines splits up into four, and the other into six lines; Preston
has given many other examples of these quartets and sextets, and has
shown that the change in the frequency, which, according to the simple
theory indicated, should be the same for all lines, actually varies
considerably from one line to another, many lines showing no appreciable
displacement. The splitting up of a single line into a quartet or sextet
indicates, from the point of view of the ion theory, that the line must
have its origin in a system consisting of more than one ion. A single
ion having only three degrees of freedom can only have three periods.
When there is no magnetic force acting on the ion these periods are
equal, but though under the action of a magnetic force they are
separated, their number cannot be increased. When therefore we get four
or more lines, the inference is that the system giving the lines must
have at least four degrees of freedom, and therefore must consist of
more than one ion. The theory of a system of ions mutually influencing
each other shows, as we should expect, that the effects are more complex
than in the case of a single ion, and that the change in the frequency
is not necessarily the same for all systems (see J. J. Thomson, _Proc.
Camb. Phil. Soc._ 13, p. 39). Preston[49] and Runge and Paschen have
proved that, in some cases at any rate, the change in the frequency of
the different lines is of such a character that they can be grouped into
series such that each line in the series has the same change in
frequency for the same magnetic force, and, moreover, that homologous
lines in the spectra of different metals belonging to the same group
have the same change in frequency.
A very remarkable case of the Zeeman effect has been discovered by H.
Becquerel and Deslandres (_Comptes rendus_, 127, p. 18). They found
lines in iron when the most deflected components are those polarized in
the plane at right angles to the magnetic force. On the simple theory
the light polarized in this way is not affected. Thus the behaviour of
the spectrum in the magnetic field promises to throw great light on the
nature of radiation, and perhaps on the constitution of the elements.
The study of these effects has been greatly facilitated by the invention
by Michelson[50] of the echelon spectroscope.
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