Encyclopedia of Diet: A Treatise on the Food Question, Vol. 1Christian, Eugene
Science
Encyclopedia of Diet: A Treatise on the Food Question, Vol. 1
Christian, Eugene
Diet; Diet in disease; Food
By this method the air is cooled down until it liquefies.
At normal atmospheric pressure it liquefies at a temperature of
--312.6°F., but under pressure of about 585 pounds it liquefies
at a temperature of --220°F. After the air has been liquefied, it
is allowed to go back to vapor by exposing it to the surrounding
heat of the atmosphere, and this vaporization separates the
nitrogen from the oxygen, as the nitrogen boils at a temperature of
--318°F., while the oxygen boils at a temperature of --294°F. There
is a difference of about 24° in the boiling points of these two
gases, which at this low point amounts to more than the difference
between the boiling points of alcohol and water, and this
difference is sufficient to separate the oxygen from the nitrogen.
Production of oxygen by the liquefaction of air is the latest,
cheapest, and most approved method, and is now becoming extensively
used in obtaining both oxygen and nitrogen for commercial use.
[Sidenote: Properties of oxygen]
Oxygen is tasteless and odorless. It is slightly heavier than air. When
subjected to an extremely high pressure and low temperature it becomes
liquid.
CHEMICAL ACTION OF OXYGEN
(a) _Upon Substances_
[Sidenote: Effect of air upon iron and wood]
Upon some substances oxygen acts at ordinary temperature. Iron becomes
covered with rust when exposed to air and moisture. Wood and other
vegetable and animal substances undergo slow decomposition when exposed
to the air. This is partly due to the action of oxygen at ordinary
temperature.
[Sidenote: Pure oxygen aids combustion]
A splinter of wood will burn brilliantly in a jar of pure oxygen, and
much more rapidly than in common air. Pure oxygen gas will cause many
substances to burn which will not burn in air. Iron can be burned in
pure oxygen, leaving only a reddish powder.
[Sidenote: Formation of iron-rust]
When iron rusts the carbon dioxid and water vapor combine chemically
with the iron, and form what is known as a basic hydroxid or carbonate
of iron. The process is somewhat complex. When iron burns in oxygen a
red powder is formed--ferric oxid, Fe₂O₃. Iron dissolves in water, or
moisture from the air containing carbonic acid, forming acid ferrous
carbonate--
Fe + 2H₂CO₃ = FeH₂(CO₃)₂ + H₂
Iron + Carbonic acid = Acid ferrous carbonate + Hydrogen
This acid ferrous carbonate, on drying or further oxidation, is
converted into _iron-rust_. If we represent _iron-rust_ by the formula
Fe₂O₃. 2Fe(OH)₃, the equation is as follows:
4FeH₂(CO₃)₂ + O₂ = Fe₂O₃. 2Fe(OH)₃ + H₂O + 8CO₂
Acid ferrous carbonate + Oxygen = Iron-rust + Water + Carbon dioxid
(b) _In Living Bodies_
The most interesting action of oxygen at ordinary temperature, however,
is that which takes place in our bodies and the bodies of all other
animals.
[Sidenote: Rate of blood circulation]
[Sidenote: Oxidation of waste matter]
Public-domain text, read in full here on John Shaqi.
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