Essays: Scientific, Political, & Speculative; Vol. 1 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.Spencer, Herbert
Philosophy
Essays: Scientific, Political, & Speculative; Vol. 1 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.
Spencer, Herbert
Philosophy; Political science; Science
There has to be added one further class of phenomena, congruous with
those above named, which here specially concerns us. Looking generally
at chemical unions, we see that the heat evolved usually decreases as
the degree of composition, and consequent massiveness, of the molecules,
increases. In the first place, we have the fact that during the
formation of simple compounds the heat evolved is much greater than that
which is evolved during the formation of complex compounds: the
elements, when uniting with one another, usually give out much heat;
while, when the compounds they form are recompounded, but little heat is
given out; and, as shown by the experiments of Prof. Andrews, the heat
given out during the union of acids and bases is habitually smaller
where the molecular weight of the base is greater. Then, in the second
place, we see that among the elements themselves, the unions of those
having low molecular weights result in far more heat than do the unions
of those having high molecular weights. If we proceed on the supposition
that the so-called elements are compounds, and if this law, if not
universal, holds of undecomposable substances as of decomposable, then
there are two implications. The one is that those compoundings and
recompoundings by which the elements were formed, must have been
accompanied by degrees of heat exceeding any degrees of heat known to
us. The other is that among these compoundings and recompoundings
themselves, those by which the small-moleculed elements were formed
produced more intense heat than those by which the large-moleculed
elements were formed: the elements formed by the final recompoundings
being necessarily later in origin, and at the same time less stable,
than the earlier-formed ones.
NOTE II. May we from these propositions, and especially from the last,
draw any conclusions respecting the evolution of heat during nebular
condensation? And do such conclusions affect in any way the conclusions
now current?
In the first place, it seems inferable from physico-chemical facts at
large, that only through the instrumentality of those combinations which
formed the elements, did the concentration of diffused nebulous matter
into concrete masses become possible. If we remember that hydrogen and
oxygen in their uncombined states oppose, the one an insuperable and the
other an almost insuperable, resistance to liquefaction, while when
combined the compound assumes the liquid state with facility, we may
suspect that in like manner the simpler types of matter out of which the
elements were formed, could not have been reduced even to such degrees
of density as the known gases show us, without what we may call
proto-chemical unions: the implication being that after the heat
resulting from each of such proto-chemical unions had escaped, mutual
gravitation of the parts was able to produce further condensation of the
nebulous mass.
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