Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.Spencer, Herbert
Philosophy
Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.
Spencer, Herbert
Philosophy; Political science; Science
The substances which exhibit most conspicuously the phenomena of
statical electricity are distinguished either by the chemical
complexity of their molecules, or else by the compositeness of their
molecules produced allotropically or isomerically, or else by both.
The simple substances electrically excited by friction, as carbon and
sulphur, are those having several allotropic states—those capable of
forming multiple molecules. The conchoidal fracture of the diamond and
of roll-sulphur, suggest some colloidal form of aggregation, regarded
by Prof. Graham as a form in which the molecules are united into {181}
relatively-large groups.[23] In such compound inorganic substances as
glass, we have, besides the chemical complexity, this same conchoidal
fracture which, along with other evidence, shows glass to be a colloid;
and the colloidal form of molecule is to be similarly inferred as
characterizing resin, amber, &c. That dry animal substances, such as
silk and hair, are formed of extremely-large molecules, we have clear
proof; since these, chemically complex in a high degree, also have
their components united in high multiples. It needs but to name the
fact that non-electric and conducting substances, such as the metals,
acids, water, &c., have relatively-simple molecules, to make it clear
that the capacity for developing statical electricity depends in some
way upon the presence of molecules of highly composite kinds. And
there is even still more conclusive proof than that yielded by the
contrast between these groups—the proof furnished by the fact that
the same substance may be a conductor or a non-conductor, according
to its form of molecular aggregation. Thus selenium when crystalline
is a conductor, but when in that allotropic state called amorphous,
or non-crystalline, it is a good non-conductor. That is, accepting
Prof. Graham’s interpretation of these states, when its molecules are
arranged simply, it is a conductor, but when they are compounded into
large groups it is a non-conductor, and, by implication, an electric.
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