Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.Spencer, Herbert
Philosophy
Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.
Spencer, Herbert
Philosophy; Political science; Science
So far, then, the _à priori_ inference that a peculiar form of
molecular perturbation will result when two unlike substances, one of
which or each of which consists of {182} highly-compounded molecules,
are made to act on one another, is justified _a posteriori_. And now,
instead of asking generally what will happen, let us ask what may
be inferred to happen in a special case. A piece of glass is rubbed
by silk. The large colloidal molecules forming the surface of each,
are made to disturb one another. This is an inference about which
there will, I suppose, be no dispute; since it is that assumed in
the now-established doctrine of the correlation of heat and motion.
Besides the effect which, as wholes the molecules mutually produce,
there is the effect produced on one another by certain of their
components. Such of these as have times of oscillation which differ,
but not very widely, generate mutual perturbations that are equal and
opposite. Could these perturbations be readily propagated away from
the surface of contact through either mass, the effect would quickly
dissipate, as in the case of metals; but, for the reason given above,
these perturbations cannot be transferred with ease to the homologous
members of the compound molecules behind. Hence the mechanical force
of the friction, transformed into the molecular movements of these
superficial constituent molecules, exists in them as _intense_ mutual
perturbations, which, unable to diffuse, are limited to the surfaces,
and, indeed, to those parts of the surfaces that have acted on one
another. In other words, the two surfaces become charged with two equal
and opposite molecular perturbations—perturbations which, cancelling
one another if the surfaces are kept in contact, cannot do this if
the surfaces are parted; but can then cancel one another only if a
conductor is interposed.
Let me briefly point out some apparent agreements between the
corollaries from this hypothesis, and the observed phenomena.
We have, first, an interpretation of the fact, otherwise seeming so
anomalous, that this form of electrical excitement is _superficial_.
That there should be a mode of {183} activity limited to the surface
of a substance, is difficult to understand in the absence of some
conception of the kind suggested.
We have an explanation of the truth, insisted on by Faraday, that
there can be no charge of one kind of electricity obtained, without
a corresponding charge of the opposite kind. For it is a necessary
implication of the hypothesis above set forth, that no molecular
perturbation of the nature described, can be produced, without there
being simultaneously produced a counter-perturbation exactly equal to
it.
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