Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
408. Boracic acid was raised to the highest possible temperature by an
oxy-hydrogen flame (401.), yet it gained no conducting powers sufficient to
affect the galvanometer, and underwent no apparent voltaic decomposition.
It seemed to be quite as bad a conductor as air. Green bottle-glass, heated
in the same manner, did not gain conducting power sensible to the
galvanometer. Flint glass, when highly heated, did conduct a little and
decompose; and as the proportion of potash or oxide of lead was increased
in the glass, the effects were more powerful. Those glasses, consisting of
boracic acid on the one hand, and oxide of lead or potassa on the other,
show the assumption of conducting power upon fusion and the accompanying
decomposition very well.
409. I was very anxious to try the general experiment with sulphuric acid,
of about specific gravity 1.783, containing that proportion of water which
gives it the power of crystallizing at 40 deg. Fahr.; but I found it impossible
to obtain it so that I could be sure the whole would congeal even at 0 deg.
Fahr. A ten-thousandth part of water, more or less than necessary, would,
upon cooling the whole, cause a portion of uncongealable liquid to
separate, and that remaining in the interstices of the solid mass, and
moistening the planes of division, would prevent the correct observation of
the phenomena due to entire solidification and subsequent liquefaction.
410. With regard to the substances on which conducting power is thus
conferred by liquidity, the degree of power so given is generally very
great. Water is that body in which this acquired power is feeblest. In the
various oxides, chlorides, salts, &c. &c., it is given in a much higher
degree. I have not had time to measure the conducting power in these cases,
but it is apparently some hundred times that of pure water. The increased
conducting power known to be given to water by the addition of salts, would
seem to be in a great degree dependent upon the high conducting power of
these bodies when in the liquid state, that state being given them for the
time, not by heat but solution in the water[A].
[A] See a doubt on this point at 1356.--_Dec. 1838._
411. Whether the conducting power of these liquefied bodies is a
consequence of their decomposition or not (413.), or whether the two
actions of conduction and decomposition are essentially connected or not,
would introduce no difference affecting the probable accuracy of the
preceding statement.
412. This _general assumption of conducting power_ by bodies as soon as
they pass from the solid to the liquid state, offers a new and
extraordinary character, the existence of which, as far as I know, has not
before been suspected; and it seems importantly connected with some
properties and relations of the particles of matter which I may now briefly
point out.
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