Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
413. In almost all the instances, as yet observed, which are governed by
this law, the substances experimented with have been those which were not
only compound bodies, but such as contain elements known to arrange
themselves at the opposite poles; and were also such as could be
_decomposed_ by the electrical current. When conduction took place,
decomposition occurred; when decomposition ceased, conduction ceased also;
and it becomes a fair and an important question, Whether the conduction
itself may not, wherever the law holds good, be a consequence not merely of
the capability, but of the act of decomposition? And that question may be
accompanied by another, namely, Whether solidification does not prevent
conduction, merely by chaining the particles to their places, under the
influence of aggregation, and preventing their final separation in the
manner necessary for decomposition?
414. But, on the other hand, there is one substance (and others may occur),
the _per-iodide of mercury_, which, being experimented with like the others
(400.), was found to insulate when solid, and to acquire conducting power
when fluid; yet it did not seem to undergo decomposition in the latter
case.
415. Again, there are many substances which contain elements such as would
be expected to arrange themselves at the opposite poles of the pile, and
therefore in that respect fitted for decomposition, which yet do not
conduct. Amongst these are the iodide of sulphur, per-iodide of zinc,
per-chloride of tin, chloride of arsenic, hydrated chloride of arsenic,
acetic acid, orpiment, realgar, artificial camphor, &c.; and from these it
might perhaps be assumed that decomposition is dependent upon conducting
power, and not the latter upon the former. The true relation, however, of
conduction and decomposition in those bodies governed by the general law
which it is the object of this paper to establish, can only be
satisfactorily made out from a far more extensive series of observations
than those I have yet been able to supply[A].
[A] See 673, &c. &c.--_Dec. 1838._
416. The relation, under this law, of the conducting power for electricity
to that for heat, is very remarkable, and seems to imply a natural
dependence of the two. As the solid becomes a fluid, it loses almost
entirely the power of conduction for heat, but gains in a high degree that
for electricity; but as it reverts hack to the solid state, it gains the
power of conducting heat, and loses that of conducting electricity. If,
therefore, the properties are not incompatible, still they are most
strongly contrasted, one being lost as the other is gained. We may hope,
perhaps, hereafter to understand the physical reason of this very
extraordinary relation of the two conducting powers, both of which appear
to be directly connected with the corpuscular condition of the substances
concerned.
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