Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
417. The assumption of conducting power and a decomposable condition by
liquefaction, promises new opportunities of, and great facilities in,
voltaic decomposition. Thus, such bodies as the oxides, chlorides,
cyanides, sulpho-cyanides, fluorides, certain vitreous mixtures, &c. &c.,
may be submitted to the action of the voltaic battery under new
circumstances; and indeed I have already been able, with ten pairs of
plates, to decompose common salt, chloride of magnesium, borax, &c. &c.,
and to obtain sodium, magnesium, boron, &c., in their separate states.
S 10. _On Conducting Power generally._[A]
[A] In reference to this S refer to 983 in series viii., and the
results connected with it.--_Dec. 1838._
418. It is not my intention here to enter into an examination of all the
circumstances connected with conducting power, but to record certain facts
and observations which have arisen during recent inquiries, as additions to
the general stock of knowledge relating to this point of electrical
science.
419. I was anxious, in the first place, to obtain some idea of the
conducting power of ice and solid salts for electricity of high tension
(392.), that a comparison might be made between it and the large accession
of the same power gained upon liquefaction. For this purpose the large
electrical machine (290.) was brought into excellent action, its conductor
connected with a delicate gold-leaf electrometer, and also with the platina
inclosed in the ice (383.), whilst the tin case was connected with the
discharging train (292.). On working the machine moderately, the gold
leaves barely separated; on working it rapidly, they could be opened nearly
two inches. In this instance the tin case was five-eighths of an inch in
width; and as, after the experiment, the platina plate was found very
nearly in the middle of the ice, the average thickness of the latter had
been five-sixteenths of an inch, and the extent of surface of contact with
tin and platina fourteen square inches (384.). Yet, under these
circumstances, it was but just able to conduct the small quantity of
electricity which this machine could evolve (371.), even when of a tension
competent to open the leaves two inches; no wonder, therefore, that it
could not conduct any sensible portion of the electricity of the troughs
(384.), which, though almost infinitely surpassing that of the machine in
quantity, had a tension so low as not to be sensible to an electrometer.
420. In another experiment, the tin case was only four-eighths of an inch
in width, and it was found afterwards that the platina had been not quite
one-eighth of an inch distant in the ice from one side of the tin vessel.
When this was introduced into the course of the electricity from the
machine (419.), the gold leaves could be opened, but not more than half an
inch; the thinness of the ice favouring the conduction of the electricity,
and permitting the same quantity to pass in the same time, though of a much
lower tension.
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