Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
[A] In reference to this subject see now electrolytic induction and
discharge, Series XII. P viii. 1343-1351, &c.--_Dec. 1838._
522. That the actions, of whatever kind they may be, take place frequently
in oblique directions is evident from the circumstance of those particles
being included which in numerous cases are not in a line between the poles.
Thus, when wires are used as poles in a glass of solution, the
decompositions and recompositions occur to the right or left of the direct
line between the poles, and indeed in every part to which the currents
extend, as is proved by many experiments, and must therefore often occur
between particles obliquely placed as respects the current itself; and when
a metallic vessel containing the solution is made one pole, whilst a mere
point or wire is used for the other, the decompositions and recompositions
must frequently be still more oblique to the course of the currents.
523. The theory which I have ventured to put forth (almost) requires an
admission, that in a compound body capable of electro-chemical
decomposition the elementary particles have a mutual relation to, and
influence upon each other, extending beyond those with which they are
immediately combined. Thus in water, a particle of hydrogen in combination
with oxygen is considered as not altogether indifferent to other particles
of oxygen, although they are combined with other particles of hydrogen; but
to have an affinity or attraction towards them, which, though it does not
at all approach in force, under ordinary circumstances, to that by which it
is combined with its own particle, can, under the electric influence,
exerted in a definite direction, be made even to surpass it. This general
relation of particles already in combination to other particles with which
they are not combined, is sufficiently distinct in numerous results of a
purely chemical character; especially in those where partial decompositions
only take place, and in Berthollet's experiments on the effects of quantity
upon affinity: and it probably has a direct relation to, and connexion
with, attraction of aggregation, both in solids and fluids. It is a
remarkable circumstance, that in gases and vapours, where the attraction of
aggregation ceases, there likewise the decomposing powers of electricity
apparently cease, and there also the chemical action of quantity is no
longer evident. It seems not unlikely, that the inability to suffer
decomposition in these cases may be dependent upon the absence of that
mutual attractive relation of the particles which is the cause of
aggregation.
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