Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
524. I hope I have now distinctly stated, although in general terms, the
view I entertain of the cause of electro-chemical decomposition, _as far as
that cause can at present be traced and understood_. I conceive the effects
to arise from forces which are _internal_, relative to the matter under
decomposition--and _not external_, as they might be considered, if directly
dependent upon the poles. I suppose that the effects are due to a
modification, by the electric current, of the chemical affinity of the
particles through or by which that current is passing, giving them the
power of acting more forcibly in one direction than in another, and
consequently making them travel by a series of successive decompositions
and recompositions in opposite directions, and finally causing their
expulsion or exclusion at the boundaries of the body under decomposition,
in the direction of the current, _and that_ in larger or smaller
quantities, according as the current is more or less powerful (377.). I
think, therefore, it would be more philosophical, and more directly
expressive of the facts, to speak of such a body, in relation to the
current passing through it, rather than to the poles, as they are usually
called, in contact with it; and say that whilst under decomposition,
oxygen, chlorine, iodine, acids, &c., are rendered at its negative
extremity, and combustibles, metals, alkalies, bases, &c., at its positive
extremity (467.), I do not believe that a substance can be transferred in
the electric current beyond the point where it ceases to find particles
with which it can combine; and I may refer to the experiments made in air
(465.) and in water (495.), already quoted, for facts illustrating these
views in the first instance; to which I will now add others.
525. In order to show the dependence of the decomposition and transfer of
elements upon the chemical affinity of the substances present, experiments
were made upon sulphuric acid in the following manner. Dilute sulphuric
acid was prepared: its specific gravity was 1.0212. A solution of sulphate
of soda was also prepared, of such strength that a measure of it contained
exactly as much sulphuric acid as an equal measure of the diluted acid just
referred to. A solution of pure soda, and another of pure ammonia, were
likewise prepared, of such strengths that a measure of either should be
exactly neutralized by a measure of the prepared sulphuric acid.
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