Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
528. In comparing the difference of acid in A and B, the necessary equality
of weight was considered as of no consequence, because the solution was at
first neutral, and would not, therefore, affect the test liquids, and all
the evolved acid would be in B, and the free alkali in A. The solution in A
required 3.2 measures of the prepared acid (525.) to neutralize it, and the
solution in B required also 3.2 measures of the soda solution (525.) to
neutralize it. As the asbestus must have removed a little acid and alkali
from the glasses, these quantities are by so much too small; and therefore
it would appear that about a tenth of the acid originally in the vessel A
had been transferred into B during the continuance of the electric action.
529. In another similar experiment, whilst a thirty-fifth part of the acid
passed from _a_ to _b_; in the free acid vessels, between a tenth and an
eleventh passed from A to B in the combined acid vessels. Other experiments
of the same kind gave similar results.
530. The variation of electro-chemical decomposition, the transfer of
elements and their accumulation at the poles, according as the substance
submitted to action consists of particles opposed more or less in their
chemical affinity, together with the consequent influence of the latter
circumstances, are sufficiently obvious in these cases, where sulphuric
acid is acted upon in the _same quantity_ by the _same_ electric current,
but in one case opposed to the comparatively weak affinity of water for it,
and in the other to the stronger one of soda. In the latter case the
quantity transferred is from two and a half to three times what it is in
the former; and it appears therefore very evident that the transfer is
greatly dependent upon the mutual action of the particles of the
decomposing bodies[A].
[A] See the note to (675.),--_Dec. 1838._
531. In some of the experiments the acid from the vessels _a_ and _b_ was
neutralized by ammonia, then evaporated to dryness, heated to redness, and
the residue examined for sulphates. In these cases more sulphate was always
obtained from _a_ than from _b_; showing that it had been impossible to
exclude saline bases (derived from the asbestus, the glass, or perhaps
impurities originally in the acid,) and that they had helped in
transferring the acid into _b_. But the quantity was small, and the acid
was principally transferred by relation to the water present.
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