Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
526. Four glass cups were then arranged, as in fig. 55; seventeen measures
of the free sulphuric acid (525.) were put into each of the vessels _a_ and
_b_, and seventeen measures of the solution of sulphate of soda into each
of the vessels A and B. Asbestus, which had been well-washed in acid, acted
upon by the voltaic pile, well-washed in water, and dried by pressure, was
used to connect _a_ with _b_ and A with B, the portions being as equal as
they could be made in quantity, and cut as short as was consistent with
their performing the part of effectual communications, _b_ and A were
connected by two platina plates or poles soldered to the extremities of one
wire, and the cups _a_ and B were by similar platina plates connected with
a voltaic battery of forty pairs of plates four inches square, that in _a_
being connected with the negative, and that in B with the positive pole.
The battery, which was not powerfully charged, was retained in
communication above half an hour. In this manner it was certain that the
same electric current had passed through _a b_ and A B, and that in each
instance the same quantity and strength of acid had been submitted to its
action, but in one case merely dissolved in water, and in the other
dissolved and also combined with an alkali.
527. On breaking the connexion with the battery, the portions of asbestus
were lifted out, and the drops hanging at the ends allowed to fall each
into its respective vessel. The acids in _a_ and _b_ were then first
compared, for which purpose two evaporating dishes were balanced, and the
acid from _a_ put into one, and that from _b_ into the other; but as one
was a little heavier than the other, a small drop was transferred from the
heavier to the lighter, and the two rendered equal in weight. Being
neutralized by the addition of the soda solution (525.), that from _a_, or
the negative vessel, required 15 parts of the soda solution, and that from
_b_, or the positive vessel, required 16.3 parts. That the sum of these is
not 34 parts is principally due to the acid removed with the asbestus; but
taking the mean of 15.65 parts, it would appear that a twenty-fourth part
of the acid originally in the vessel _a_ had passed, through the influence
of the electric current, from _a_ into _b_.
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