Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
555. On the other hand, if a strong solution of nitrate of ammonia be
decomposed, oxygen appears at the positive pole, and hydrogen, with
sometimes nitrogen, at the negative pole. If fused nitrate of ammonia be
employed, hydrogen appears at the negative pole, mingled with a little
nitrogen. Strong nitric acid yields plenty of oxygen at the positive pole,
but no gas (only nitrous acid) at the negative pole. Weak nitric acid
yields the oxygen and hydrogen of the water present, the acid apparently
remaining unchanged. Strong nitric acid with nitrate of ammonia dissolved
in it, yields a gas at the negative pole, of which the greater part is
hydrogen, but apparently a little nitrogen is present. I believe, that in
some of these cases a little nitrogen appeared at the negative pole. I
suspect, however, that in all these, and in all former cases, the
appearance of the nitrogen at the positive or negative pole is entirely a
secondary effect, and not an immediate consequence of the decomposing power
of the electric current[A].
[A] Refer for proof of the truth of this supposition to 748, 752,
&c.--_Dec. 1838._
556. A few observations on what are called the _poles_ of the voltaic
battery now seem necessary. The poles are merely the surfaces or doors by
which the electricity enters into or passes out of the substance suffering
decomposition. They limit the extent of that substance in the course of the
electric current, being its _terminations_ in that direction: Hence the
elements evolved pass so far and no further.
557. Metals make admirable poles, in consequence of their high conducting
power, their immiscibility with the substances generally acted upon, their
solid form, and the opportunity afforded of selecting such as are not
chemically acted upon by ordinary substances.
558. Water makes a pole of difficult application, except in a few cases
(494.), because of its small conducting power, its miscibility with most of
the substances acted upon, and its general relation to them in respect to
chemical affinity. It consists of elements, which in their electrical and
chemical relations are directly and powerfully opposed, yet combining to
produce a body more neutral in its character than any other. So that there
are but few substances which do not come into relation, by chemical
affinity, with water or one of its elements; and therefore either the water
or its elements are transferred and assist in transferring the infinite
variety of bodies which, in association with it, can be placed in the
course of the electric current. Hence the reason why it so rarely happens
that the evolved substances rest at the first surface of the water, and why
it therefore does not exhibit the ordinary action of a pole.
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