Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
559. Air, however, and some gases are free from the latter objection, and
may be used as poles in many cases (461, &c.); but, in consequence of the
extremely low degree of conducting power belonging to them, they cannot be
employed with the voltaic apparatus. This limits their use; for the voltaic
apparatus is the only one as yet discovered which supplies sufficient
quantity of electricity (371. 376.) to effect electro-chemical
decomposition with facility.
560. When the poles are liable to the chemical action of the substances
evolved, either simply in consequence of their natural relation to them, or
of that relation aided by the influence of the current (518.), then they
suffer corrosion, and the parts dissolved are subject to transference, in
the same manner as the particles of the body originally under
decomposition. An immense series of phenomena of this kind might be quoted
in support of the view I have taken of the cause of electro-chemical
decomposition, and the transfer and evolution of the elements. Thus platina
being made the positive and negative poles in a solution of sulphate of
soda, has no affinity or attraction for the oxygen, hydrogen, acid, or
alkali evolved, and refuses to combine with or retain them. Zinc can
combine with the oxygen and acid; at the positive pole it does combine, and
immediately begins to travel as oxide towards the negative pole. Charcoal,
which cannot combine with the metals, if made the negative pole in a
metallic solution, refuses to unite to the bodies which are ejected from
the solution upon its surface; but if made the positive pole in a dilute
solution of sulphuric acid, it is capable of combining with the oxygen
evolved there, and consequently unites with it, producing both carbonic
acid and carbonic oxide in abundance.
561. A great advantage is frequently supplied, by the opportunity afforded
amongst the metals of selecting a substance for the pole, which shall or
shall not be acted upon by the elements to be evolved. The consequent use
of platina is notorious. In the decomposition of sulphuret of silver and
other sulphurets, a positive silver pole is superior to a platina one,
because in the former case the sulphur evolved there combines with the
silver, and the decomposition of the original sulphuret is rendered
evident; whereas in the latter case it is dissipated, and the assurance of
its separation at the pole not easily obtained.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account