Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
585. This remarkable property was conferred upon platina when it was made
the positive pole in sulphuric acid of specific gravity 1.336, or when it
was considerably weaker, or when stronger, even up to the strength of oil
of vitriol. Strong and dilute nitric acid, dilute acetic acid, solutions of
tartaric, citric, and oxalic acids, were used with equal success. When
muriatic acid was used, the plates acquired the power of condensing the
oxygen and hydrogen, but in a much inferior degree.
586. Plates which were made positive in solution of caustic potassa did not
show any sensible action upon the mixed oxygen and hydrogen. Other plates
made positive in solutions of carbonates of potassa and soda exhibited the
action, but only in a feeble degree.
587. When a neutral solution of sulphate of soda, or of nitre, or of
chlorate of potassa, or of phosphate of potassa, or acetate of potassa, or
sulphate of copper, was used, the plates, rendered positive in them for
four minutes, and then washed in water, acted very readily and powerfully
on the mixed oxygen and hydrogen.
588. It became a very important point, in reference to the _cause_ of this
action of the platina, to determine whether the _positive_ pole _only_
could confer it (567.), or whether, notwithstanding the numerous contrary
cases, the _negative_ pole might not have the power when such circumstances
as could interfere with or prevent the action were avoided. Three plates
were therefore rendered negative, for four minutes in diluted sulphuric
acid of specific gravity 1.336, washed in distilled water, and put into
mixed oxygen and hydrogen. _All_ of them _acted_, though not so strongly as
they would have done if they had been rendered positive. Each combined
about a cubical inch and a quarter of the gases in twenty-five minutes. On
every repetition of the experiment the same result was obtained; and when
the plates were retained in distilled water for ten or twelve minutes,
before being introduced into the gas (582.), the action was very much
quickened.
589. But when there was any metallic or other substance present in the
acid, which could be precipitated on the negative plate, then that plate
ceased to act upon the mixed oxygen and hydrogen.
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