Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
590. These experiments led to the expectation that the power of causing
oxygen and hydrogen to combine, which could be conferred upon any piece of
platina by making it the positive pole of a voltaic pile, was not
essentially dependent upon the action of the pile, or upon any structure or
arrangement of parts it might receive whilst in association with it, but
belonged to the platina _at all times_, and was _always effective_ when the
surface was _perfectly clean_. And though, when made the _positive_ pole of
the pile in acids, the circumstances might well be considered as those
which would cleanse the surface of the platina in the most effectual
manner, it did not seem impossible that ordinary operations should produce
the same result, although in a less eminent degree.
591. Accordingly, a platina plate (569.) was cleaned by being rubbed with a
cork, a little water, and some coal-fire ashes upon a glass plate: being
washed, it was put into mixed oxygen and hydrogen, and was found to act at
first slowly, and then more rapidly. In an hour, a cubical inch and a half
had disappeared.
592. Other plates were cleaned with ordinary sand-paper and water; others
with chalk and water; others with emery and water; others, again, with
black oxide of manganese and water; and others with a piece of charcoal and
water. All of these acted in tubes of oxygen and hydrogen, causing
combination of the gases. The action was by no means so powerful as that
produced by plates having been in communication with the battery; but from
one to two cubical inches of the gases disappeared, in periods extending
from twenty-five to eighty or ninety minutes.
593. Upon cleaning the plates with a cork, ground emery, and dilute
sulphuric acid, they were found to act still better. In order to simplify
the conditions, the cork was dismissed, and a piece of platina foil used
instead; still the effect took place. Then the acid was dismissed, and a
solution of _potassa_ used, but the effect occurred as before.
594. These results are abundantly sufficient to show that the mere
mechanical cleansing of the surface of the platina is sufficient to enable
it to exert its combining power over oxygen and hydrogen at common
temperatures.
595. I now tried the effect of heat in conferring this property upon
platina (584.). Plates which had no action on the mixture of oxygen and
hydrogen were heated by the flame of a freshly trimmed spirit-lamp, urged
by a mouth blowpipe, and when cold were put into tubes of the mixed gases:
they acted slowly at first, but after two or three hours condensed nearly
all the gases.
Public-domain text, read in full here on John Shaqi.
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