Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
599. The action of alkalies and acids in giving platina this property was
now experimentally examined. Platina plates (569.) having no action on
mixed oxygen and hydrogen, being boiled in a solution of caustic potassa,
washed, and then put into the gases, were found occasionally to act pretty
well, but at other times to fail. In the latter case I concluded that the
impurity upon the surface of the platina was of a nature not to be removed
by the mere solvent action of the alkali, for when the plates were rubbed
with a little emery, and the same solution of alkali (592.), they became
active.
600. The action of acids was far more constant and satisfactory. A platina
plate was boiled in dilute nitric acid: being washed and put into mixed
oxygen and hydrogen gases, it acted well. Other plates were boiled in
strong nitric acid for periods extending from half a minute to four
minutes, and then being washed in distilled water, were found to act very
well, condensing one cubic inch and a half of gas in the space of eight or
nine minutes, and rendering the tube warm (570.).
601. Strong sulphuric acid was very effectual in rendering the platina
active. A plate (569.) was heated in it for a minute, then washed and put
into the mixed oxygen and hydrogen, upon which it acted as well as if it
had been made the positive pole of a voltaic pile (570.).
602. Plates which, after being heated or electrized in alkali, or after
other treatment, were found inert, immediately received power by being
dipped for a minute or two, or even only for an instant, into hot oil of
vitriol, and then into water.
603. When the plate was dipped into the oil of vitriol, taken out, and then
heated so as to drive off the acid, it did not act, in consequence of the
impurity left by the acid upon its surface.
604. Vegetable acids, as acetic and tartaric, sometimes rendered inert
platina active, at other times not. This, I believe, depended upon the
character of the matter previously soiling the plates, and which may easily
be supposed to be sometimes of such a nature as to be removed by these
acids, and at other times not. Weak sulphuric acid showed the same
difference, but strong sulphuric acid (601.) never failed in its action.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account