Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
596. A plate of platina, which was about one inch wide and two and
three-quarters in length, and which had not been used in any of the
preceding experiments, was curved a little so as to enter a tube, and left
in a mixture of oxygen and hydrogen for thirteen hours: not the slightest
action or combination of the gases occurred. It was withdrawn at the
pneumatic trough from the gas through the water, heated red-hot by the
spirit-lamp and blowpipe, and then returned when cold into the _same_
portion of gas. In the course of a few minutes diminution of the gases
could be observed, and in forty-five minutes about one cubical inch and a
quarter had disappeared. In many other experiments platina plates when
heated were found to acquire the power of combining oxygen and hydrogen.
597. But it happened not infrequently that plates, after being heated,
showed no power of combining oxygen and hydrogen gases, though left
undisturbed in them for two hours. Sometimes also it would happen that a
plate which, having been heated to dull redness, acted feebly, upon being
heated to whiteness ceased to act; and at other times a plate which, having
been slightly heated, did not act, was rendered active by a more powerful
ignition.
598. Though thus uncertain in its action, and though often diminishing the
power given to the plates at the positive pole of the pile (584.), still it
is evident that heat can render platina active, which before was inert
(595.). The cause of its occasional failure appears to be due to the
surface of the metal becoming soiled, either from something previously
adhering to it, which is made to adhere more closely by the action of the
heat, or from matter communicated from the flame of the lamp, or from the
air itself. It often happens that a polished plate of platina, when heated
by the spirit-lamp and a blowpipe, becomes dulled and clouded on its
surface by something either formed or deposited there; and this, and much
less than this, is sufficient to prevent it from exhibiting the curious
power now under consideration (634. 636.). Platina also has been said to
combine with carbon; and it is not at all unlikely that in processes of
heating, where carbon or its compounds are present, a film of such a
compound may be thus formed, and thus prevent the exhibition of the
properties belonging to _pure_ platina[A].
[A] When heat does confer the property it is only by the destruction
or dissipation of organic or other matter which had previously soiled
the plate (632. 633. 634.).--_Dec. 1838._
Public-domain text, read in full here on John Shaqi.
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