Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
609. There can remain no doubt that the property of inducing combination,
which can thus be conferred upon masses of platina and other metals by
connecting them with the poles of the battery, or by cleansing processes
either of a mechanical or chemical nature, is the same as that which was
discovered by Doebereiner[A], in 1823, to belong in so eminent a degree to
spongy platina, and which was afterwards so well experimented upon and
illustrated by MM. Dulong and Thenard[B], in 1823. The latter philosophers
even quote experiments in which a very fine platina wire, which had been
coiled up and digested in nitric, sulphuric, or muriatic acid, became
ignited when put into a jet of hydrogen gas[C]. This effect I can now
produce at pleasure with either wires or plates by the processes described
(570. 601. 605.); and by using a smaller plate cut so that it shall rest
against the glass by a few points, and yet allow the water to flow off
(fig. 59.), the loss of heat is less, the metal is assimilated somewhat to
the spongy state, and the probability of failure almost entirely removed.
[A] Annales de Chimie, tom. xxiv. p. 93.
[B] Ibid. tom. xxiii. p. 440; tom. xxiv. p. 380.
[C] Ibid. tom. xxiv. p. 383.
610. M. Doebereiner refers the effect entirely to an electric action. He
considers the platina and hydrogen as forming a voltaic element of the
ordinary kind, in which the hydrogen, being very highly positive,
represents the zinc of the usual arrangement, and like it, therefore,
attracts oxygen and combines with it[A].
[A] tom. xxiv. pp. 94, 95. Also Bibliotheque Universelle, tom. xxiv.
p. 54.
611. In the two excellent experimental papers by MM. Dulong and Thenard[A],
those philosophers show that elevation of temperature favours the action,
but does not alter its character; Sir Humphry Davy's incandescent platina
wire being the same phenomenon with Doebereiner's spongy platina. They show
that _all_ metals have this power in a greater or smaller degree, and that
it is even possessed by such bodies as charcoal, pumice, porcelain, glass,
rock crystal, &c., when their temperatures are raised; and that another of
Davy's effects, in which oxygen and hydrogen had combined slowly together
at a heat below ignition, was really dependent upon the property of the
heated glass, which it has in common with the bodies named above. They
state that liquids do not show this effect, at least that mercury, at or
below the boiling point, has not the power; that it is not due to porosity;
that the same body varies very much in its action, according to its state;
and that many other gaseous mixtures besides oxygen and hydrogen are
affected, and made to act chemically, when the temperature is raised. They
think it probable that spongy platina acquires its power from contact with
the acid evolved during its reduction, or from the heat itself to which it
is then submitted.
[A] Annales de Chimie, tom. xxiii. p. 440; tom. xxiv. p, 380.
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