Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
612. MM. Dulong and Thenard express themselves with great caution on the
theory of this action; but, referring to the decomposing power of metals on
ammonia when heated to temperatures not sufficient alone to affect the
alkali, they remark that those metals which in this case are most
efficacious, are the least so in causing the combination of oxygen and
hydrogen; whilst platina, gold, &c., which have least power of decomposing
ammonia, have most power of combining the elements of water:--from which
they are led to believe, that amongst gases, some tend to _unite_ under the
influence of metals, whilst others tend to _separate_, and that this
property varies in opposite directions with the different metals. At the
close of their second paper they observe, that the action is of a kind that
cannot be connected with any known theory; and though it is very remarkable
that the effects are transient, like those of most electrical actions, yet
they state that the greater number of the results observed by them are
inexplicable, by supposing them to be of a purely electric origin.
613. Dr. Fusinieri has also written on this subject, and given a theory
which he considers as sufficient to account for the phenomena[A]. He
expresses the immediate cause thus: "The platina determines upon its
surface a continual renovation of _concrete laminae_ of the combustible
substance of the gases or vapours, which flowing over it are burnt, pass
away, and are renewed: this combustion at the surface raises and sustains
the temperature of the metal." The combustible substance, thus reduced into
imperceptible laminae, of which the concrete parts are in contact with the
oxygen, is presumed to be in a state combinable with the oxygen at a much
lower temperature than when it is in the gaseous state, and more in analogy
with what is called the nascent condition. That combustible gases should
lose their elastic state, and become concrete, assuming the form of
exceedingly attenuated but solid strata, is considered as proved by facts,
some of which are quoted in the Giornale di Fisica for 1824[B]; and though
the theory requires that they should assume this state at high
temperatures, and though the _similar_ films of aqueous and other matter
are dissipated by the action of heat, still the facts are considered as
justifying the conclusion against all opposition of reasoning.
[A] Giornale di Fisica, &c., 1825, tom. viii. p. 259.
[B] pp. 138, 371.
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