Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
628. A third and very important consideration in favour of the mutual
action of gases under these circumstances is their perfect miscibility. If
fluid bodies capable of combining together are also capable of mixture,
_they do combine_ when they are mingled, not waiting for any other
determining circumstance; but if two such gases as oxygen and hydrogen are
put together, though they are elements having such powerful affinity as to
unite naturally under a thousand different circumstances, they do not
combine by mere mixture. Still it is evident that, from their perfect
association, the particles are in the most favourable state possible for
combination upon the supervention of any determining cause, such either as
the negative action of the platina in suppressing or annihilating, as it
were, their elasticity on its side; or the positive action of the metal in
condensing them against its surface by an attractive force; or the
influence of both together.
629. Although there are not many distinct cases of combination under the
influence of forces external to the combining particles, yet there are
sufficient to remove any difficulty which might arise on that ground. Sir
James Hull found carbonic acid and lime to remain combined under pressure
at temperatures at which they would not have remained combined if the
pressure had been removed; and I have had occasion to observe a case of
direct combination in chlorine[A], which being compressed at common
temperatures will combine with water, and form a definite crystalline
hydrate, incapable either of being formed or of existing if that pressure
be removed.
[A] Philosophical Transactions, 1823, p. 161.
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