Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
630. The course of events when platina acts upon, and combines oxygen and
hydrogen, may be stated, according to these principles, as follows. From
the influence of the circumstances mentioned (619. &c.), i.e. the
deficiency of elastic power and the attraction of the metal for the gases,
the latter, when they are in association with the former, are so far
condensed as to be brought within the action of their mutual affinities at
the existing temperature; the deficiency of elastic power, not merely
subjecting them more closely to the attractive influence of the metal, but
also bringing them into a more favourable state for union, by abstracting a
part of that power (upon which depends their elasticity,) which elsewhere
in the mass of gases is opposing their combination. The consequence of
their combination is the production of the vapour of water and an elevation
of temperature. But as the attraction of the platina for the water formed
is not greater than for the gases, if so great, (for the metal is scarcely
hygrometric,) the vapour is quickly diffused through the remaining gases;
fresh portions of this latter, therefore, come into juxtaposition with the
metal, combine, and the fresh vapour formed is also diffused, allowing new
portions of gas to be acted upon. In this way the process advances, but is
accelerated by the evolution of heat, which is known by experiment to
facilitate the combination in proportion to its intensity, and the
temperature is thus gradually exalted until ignition results.
631. The dissipation of the vapour produced at the surface of the platina,
and the contact of fresh oxygen and hydrogen with the metal, form no
difficulty in this explication. The platina is not considered as causing
the combination of any particles with itself, but only associating them
closely around it; and the compressed particles are as free to move from
the platina, being replaced by other particles, as a portion of dense air
upon the surface of the globe, or at the bottom of a deep mine, is free to
move by the slightest impulse, into the upper and rarer parts of the
atmosphere.
632. It can hardly be necessary to give any reasons why platina does not
show this effect under ordinary circumstances. It is then not sufficiently
clean (617.), and the gases are prevented from touching it, and suffering
that degree of effect which is needful to commence their combination at
common temperatures, and which they can only experience at its surface. In
fact, the very power which causes the combination of oxygen and hydrogen,
is competent, under the usual casual exposure of platina, to condense
extraneous matters upon its surface, which soiling it, take away for the
time its power of combining oxygen and hydrogen, by preventing their
contact with it (598.).
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