Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
640. But when similar experiments were made with _olefiant gas_ (the
platina plates having been made the positive poles of a voltaic pile (570.)
in acid), very different results occurred. A mixture was made of 29.2
volumes hydrogen and 14.6 volumes oxygen, being the proportions for water;
and to this was added another mixture of 3 volumes oxygen and one volume
olefiant gas, so that the olefiant gas formed but 1/40th part of the whole;
yet in this mixture the platina plate would not act in forty-five hours.
The failure was not for want of any power in the plate, for when after that
time it was taken out of this mixture and put into one of oxygen and
hydrogen, it immediately acted, and in seven minutes caused explosion of
the gas. This result was obtained several times, and when larger
proportions of olefiant gas were used, the action seemed still more
hopeless.
641. A mixture of forty-nine volumes oxygen and hydrogen (638.) with one
volume of olefiant gas had a well-prepared platina plate introduced. The
diminution of gas was scarcely sensible at the end of two hours, during
which it was watched; but on examination twenty-four hours afterwards, the
tube was found blown to pieces. The action, therefore, though it had been
very much retarded, had occurred at last, and risen to a maximum.
642. With a mixture of ninety-nine volumes of oxygen and hydrogen (638.)
with one of olefiant gas, a feeble action was evident at the end of fifty
minutes; it went on accelerating (630.) until the eighty-fifth minute, and
then became so intense that the gas exploded. Here also the retarding
effect of the olefiant gas was very beautifully illustrated.
643. Plates prepared by alkali and acid (605.) produced effects
corresponding to those just described.
644. It is perfectly clear from these experiments, that _olefiant gas_,
even in small quantities, has a very remarkable influence in preventing the
combination of oxygen and hydrogen under these circumstances, and yet
without at all injuring or affecting the power of the platina.
645. Another striking illustration of similar interference may be shown in
_carbonic oxide_; especially if contrasted with _carbonic acid_. A mixture
of one volume oxygen and hydrogen (638.) with four volumes of carbonic acid
was affected at once by a platina plate prepared with acid, &c. (605.); and
in one hour and a quarter nearly all the oxygen and hydrogen was gone.
Mixtures containing less carbonic acid were still more readily affected.
646. But when carbonic oxide was substituted for the carbonic acid, not the
slightest effect of combination was produced; and when the carbonic oxide
was only one-eighth of the whole volume, no action occurred in forty and
fifty hours. Yet the plates had not lost their power; for being taken out
and put into pure oxygen and hydrogen, they acted well and at once.
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