Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
636. The same reasons explain why the power of the platina plates in some
circumstances soon disappear, and especially upon use: MM. Dulong and
Thenard have observed the same effect with the spongy metal[A], as indeed
have all those who have used Doebereiner's instantaneous light machines. If
left in the air, if put into ordinary distilled water, if made to act upon
ordinary oxygen and hydrogen, they can still find in all these cases _that_
minute portion of impurity which, when once in contact with the surface of
the platina, is retained there, and is sufficient to prevent its full
action upon oxygen and hydrogen at common temperatures: a slight elevation
of temperature is again sufficient to compensate this effect, and cause
combination.
[A] Annales de Chimie, tom. xxiv. p. 386.
637. No state of a solid body can be conceived more favourable for the
production of the effect than that which is possessed by platina obtained
from the ammonio-muriate by heat. Its surface is most extensive and pure,
yet very accessible to the gases brought in contact with it: if placed in
impurity, the interior, as Thenard and Dulong have observed, is preserved
clean by the exterior; and as regards temperature, it is so bad a conductor
of heat, because of its divided condition, that almost all which is evolved
by the combination of the first portions of gas is retained within the
mass, exalting the tendency of the succeeding portions to combine.
* * * * *
638. I have now to notice some very extraordinary interferences with this
phenomenon, dependent, not upon the nature or condition of the metal or
other acting solid, but upon the presence of certain substances mingled
with the gases acted upon; and as I shall have occasion to speak frequently
of a mixture of oxygen and hydrogen, I wish it always to be understood that
I mean a mixture composed of one volume of oxygen to two volumes of
hydrogen, being the proportions that form water. Unless otherwise
expressed, the hydrogen was always that obtained by the action of dilute
sulphuric acid on pure zinc, and the oxygen that obtained by the action of
heat from the chlorate of potassa.
639. Mixtures of oxygen and hydrogen with _air_, containing one-fourth,
one-half, and even two-thirds of the latter, being introduced with prepared
platina plates (570. 605.) into tubes, were acted upon almost as well as if
no air were present: the retardation was far less than might have been
expected from the mere dilution and consequent obstruction to the contact
of the gases with the plates. In two hours and a half nearly all the oxygen
and hydrogen introduced as mixture was gone.
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