Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
922. It might at first be supposed that a conducting body not electrolytic,
might answer as the third substance between the zinc and the platina; and
it is true that we have some such capable of exerting chemical action upon
the metals. They must, however, be chosen from the metals themselves, for
there are no bodies of this kind except those substances and charcoal. To
decide the matter by experiment, I made the following arrangement. Melted
tin was put into a glass tube bent into the form of the letter V, fig. 78,
so as to fill the half of each limb, and two pieces of thick platina wire,
_p_, _w_, inserted, so as to have their ends immersed some depth in the
tin: the whole was then allowed to cool, and the ends _p_ and _w_ connected
with a delicate galvanometer. The part of the tube at _x_ was now reheated,
whilst the portion _y_ was retained cool. The galvanometer was immediately
influenced by the thermo-electric current produced. The heat was steadily
increased at _x_, until at last the tin and platina combined there; an
effect which is known to take place with strong chemical action and high
ignition; but not the slightest additional effect occurred at the
galvanometer. No other deflection than that due to the thermo-electric
current was observable the whole time. Hence, though a conductor, and one
capable of exerting chemical action on the tin, was used, yet, not being an
_electrolyte_, not the slightest effect of an electrical current could be
observed (947.).
923. From this it seems apparent that the peculiar character and condition
of an electrolyte is _essential_ in one part of the voltaic circuit; and
its nature being considered, good reasons appear why it and it alone should
be effectual. An electrolyte is always a compound body: it can conduct, but
only whilst decomposing. Its conduction depends upon its decomposition and
the _transmission of its particles_ in directions parallel to the current;
and so intimate is this connexion, that if their transition be stopped, the
current is stopped also; if their course be changed, its course and
direction change with them; if they proceed in one direction, it has no
power to proceed in any other than a direction invariably dependent on
them. The particles of an electrolytic body are all so mutually connected,
are in such relation with each other through their whole extent in the
direction of the current, that if the last is not disposed of, the first is
not at liberty to take up its place in the new combination which the
powerful affinity of the most active metal tends to produce; and then the
current itself is stopped; for the dependencies of the current and the
decomposition are so mutual, that whichsoever be originally determined,
i.e. the motion of the particles or the motion of the current, the other is
invariable in its concomitant production and its relation to it.
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