Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
924. Consider, then, water as an electrolyte and also as an oxidizing body.
The attraction of the zinc for the oxygen is greater, under the
circumstances, than that of the oxygen for the hydrogen; but in combining
with it, it tends to throw into circulation a current of electricity in a
certain direction. This direction is consistent (as is found by innumerable
experiments) with the transfer of the hydrogen from the zinc towards the
platina, and the transfer in the opposite direction of fresh oxygen from
the platina towards the zinc; so that the current _can pass_ in that one
line, and, whilst it passes, can consist with and favour the renewal of the
conditions upon the surface of the zinc, which at first determined both the
combination and circulation. Hence the continuance of the action there, and
the continuation of the current. It therefore appears quite as essential
that there should be an electrolyte in the circuit, in order that the
action may be transferred forward, in a _certain constant direction,_ as
that there should be an oxidizing or other body capable of acting directly
on the metal; and it also appears to be essential that these two should
merge into one, or that the principle directly active on the metal by
chemical action should be one of the _ions_ of the electrolyte used.
Whether the voltaic arrangement be excited by solution of acids, or
alkalies, or sulphurets, or by fused substances (476.), this principle has
always hitherto, as far as I am aware, been an _anion_ (943.); and I
anticipate, from a consideration of the principles of electric action, that
it must of necessity be one of that class of bodies.
Public-domain text, read in full here on John Shaqi.
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