Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
925. If the action of the sulphuric acid used in the voltaic circuit be
considered, it will be found incompetent to produce any sensible portion of
the electricity of the current by its combination with the oxide formed,
for this simple reason, it is deficient in a most essential condition: it
forms no part of an electrolyte, nor is it in relation with any other body
present in the solution which will permit of the mutual transfer of the
particles and the consequent transfer of the electricity. It is true, that
as the plane at which the acid is dissolving the oxide of zinc formed by
the action of the water, is in contact with the metal zinc, there seems no
difficulty in considering how the oxide there could communicate an
electrical state, proportionate to its own chemical action on the acid, to
the metal, which is a conductor without decomposition. But on the side of
the acid there is no substance to complete the circuit: the water, as
water, cannot conduct it, or at least only so small a proportion that it is
merely an incidental and almost inappreciable effect (970.); and it cannot
conduct it as an electrolyte, because an electrolyte conducts in
consequence of the _mutual_ relation and action of its particles; and
neither of the elements of the water, nor even the water itself, as far as
we can perceive, are _ions_ with respect to the sulphuric acid (848.)[A].
[A] It will be seen that I here agree with Sir Humphry Davy, who has
experimentally supported the opinion that acids and alkalies in
combining do not produce any current of electricity. Philosophical
Transactions, 1826, p. 398.
926. This view of the secondary character of the sulphuric acid as an agent
in the production of the voltaic current, is further confirmed by the fact,
that the current generated and transmitted is directly and exactly
proportional to the quantity of water decomposed and the quantity of zinc
oxidized (868. 991.), and is the same as that required to decompose the
same quantity of water. As, therefore, the decomposition of the water shows
that the electricity has passed by its means, there remains no other
electricity to be accounted for or to be referred to any action other than
that of the zinc and the water on each other.
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