Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
930. This view of the oxidation of the metal, or other _direct_ chemical
action upon it, being the sole cause of the production of the electric
current in the ordinary voltaic pile, is supported by the effects which
take place when alkaline or sulphuretted solutions (931. 943.) are used for
the electrolytic conductor instead of dilute sulphuric acid. It was in
elucidation of this point that the experiments without metallic contact,
and with solution of alkali as the exciting fluid, already referred to
(884.), were made.
931. Advantage was then taken of the more favourable condition offered,
when metallic contact is allowed (895.), and the experiments upon the
decomposition of bodies by a single pair of plates (899.) were repeated,
solution of caustic potassa being employed in the vessel _v_, fig. 77. in
place of dilute sulphuric acid. All the effects occurred as before: the
galvanometer was deflected; the decompositions of the solutions of iodide
of potassium, nitrate of silver, muriatic acid, and sulphate of soda ensued
at _x_; and the places where the evolved principles appeared, as well as
the deflection of the galvanometer, indicated a current in the _same
direction_ as when acid was in the vessel _v_; i.e. from the zinc through
the solution to the platina, and back by the galvanometer and substance
suffering decomposition to the zinc.
932. The similarity in the action of either dilute sulphuric acid or
potassa goes indeed far beyond this, even to the proof of identity in
_quantity_ as well as in _direction_ of the electricity produced. If a
plate of amalgamated zinc be put into a solution of potassa, it is not
sensibly acted upon; but if touched in the solution by a plate of platina,
hydrogen is evolved on the surface of the latter metal, and the zinc is
oxidized exactly as when immersed in dilute sulphuric acid (863.). I
accordingly repeated the experiment before described with weighed plates of
zinc (864. &c.), using however solution of potassa instead of dilute
sulphuric acid. Although the time required was much longer than when acid
was used, amounting to three hours for the oxidizement of 7.55 grains of
zinc, still I found that the hydrogen evolved at the platina plate was the
equivalent of the metal oxidized at the surface of the zinc. Hence the
whole of the reasoning which was applicable in the former instance applies
also here, the current being in the same direction, and its decomposing
effect in the same degree, as if acid instead of alkali had been used
(868.).
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