Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
933. The proof, therefore, appears to me complete, that the combination of
the acid with the oxide, in the former experiment, had nothing to do with
the production of the electric current; for the same current is here
produced when the action of the acid is absent, and the reverse action of
an alkali is present. I think it cannot be supposed for a moment, that the
alkali acted chemically as an acid to the oxide formed; on the contrary,
our general chemical knowledge leads to the conclusion, that the ordinary
metallic oxides act rather as acids to the alkalies; yet that kind of
action would tend to give a reverse current in the present case, if any
were due to the union of the oxide of the exciting metal with the body
which combines with it. But instead of any variation of this sort, the
direction of the electricity was constant, and its quantity also directly
proportional to the water decomposed, or the zinc oxidized. There are
reasons for believing that acids and alkalies, when in contact with metals
upon which they cannot act directly, still have a power of influencing
their attractions for oxygen (941.); but all the effects in these
experiments prove, I think, that it is the oxidation of the metal
necessarily dependent upon, and associated as it is with, the
electrolyzation of the water (921. 923.) that produces the current; and
that the acid or alkali merely acts as solvents, and by removing the
oxidized zinc, allows other portions to decompose fresh water, and so
continues the evolution or determination of the current.
934. The experiments were then varied by using solution of ammonia instead
of solution of potassa; and as it, when pure, is like water, a bad
conductor (554.), it was occasionally improved in that power by adding
sulphate of ammonia to it. But in all the cases the results were the same
as before; decompositions of the same kind were effected, and the electric
current producing these was in the same direction as in the experiments
just described.
935. In order to put the equal and similar action of acid and alkali to
stronger proof, arrangements were made as in fig. 80.; the glass vessel A
contained dilute sulphuric acid, the corresponding glass vessel B solution
of potassa, PP was a plate of platina dipping into both solutions, and ZZ
two plates of amalgamated zinc connected with a delicate galvanometer. When
these were plunged at the same time into the two vessels, there was
generally a first feeble effect, and that in favour of the alkali, i.e. the
electric current tended to pass through the vessels in the direction of the
arrow, being the reverse direction of that which the acid in A would have
produced alone: but the effect instantly ceased, and the action of the
plates in the vessels was so equal, that, being contrary because of the
contrary position of the plates, no permanent current resulted.
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