Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
936. Occasionally a zinc plate was substituted for the plate PP, and
platina plates for the plates ZZ; but this caused no difference in the
results: nor did a further change of the middle plate to copper produce any
alteration.
937. As the opposition of electro-motive pairs of plates produces results
other than those due to the mere difference of their independent actions
(1011. 1045.), I devised another form of apparatus, in which the action of
acid and alkali might be more directly compared. A cylindrical glass cup,
about two inches deep within, an inch in internal diameter, and at least a
quarter of an inch in thickness, was cut down the middle into halves, fig.
81. A broad brass ring, larger in diameter than the cup, was supplied with
a screw at one side; so that when the two halves of the cup were within the
ring, and the screw was made to press tightly against the glass, the cup
held any fluid put into it. Bibulous paper of different degrees of
permeability was then cut into pieces of such a size as to be easily
introduced between the loosened halves of the cup, and served when the
latter were tightened again to form a porous division down the middle of
the cup, sufficient to keep any two fluids on opposite sides of the paper
from mingling, except very slowly, and yet allowing them to act freely as
one _electrolyte_. The two spaces thus produced I will call the cells A and
B, fig. 82. This instrument I have found of most general application in the
investigation of the relation of fluids and metals amongst themselves and
to each other. By combining its use with that of the galvanometer, it is
easy to ascertain the relation of one metal with two fluids, or of two
metals with one fluid, or of two metals and two fluids upon each other.
938. Dilute sulphuric acid, sp. gr. 1.25, was put into the cell A, and a
strong solution of caustic potassa into the cell B; they mingled slowly
through the paper, and at last a thick crust of sulphate of potassa formed
on the side of the paper next to the alkali. A plate of clean platina was
put into each cell and connected with a delicate galvanometer, but no
electric current could be observed. Hence the _contact_ of acid with one
platina plate, and alkali with the other, was unable to produce a current;
nor was the combination of the acid with the alkali more effectual (925.).
939. When one of the platina plates was removed and a zinc plate
substituted, either amalgamated or not, a strong electric current was
produced. But, whether the zinc were in the acid whilst the platina was in
the alkali, or whether the reverse order were chosen, the electric current
was always from the zinc through the electrolyte to the platina, and back
through the galvanometer to the zinc, the current seeming to be strongest
when the zinc was in the alkali and the platina in the acid.
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