Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
949. Assuming it sufficiently proved, by the preceding experiments and
considerations, that the electro-motive action depends, when zinc, platina,
and dilute sulphuric acid are used, upon the mutual affinity of the metal
zinc and the oxygen of the water (921. 924.), it would appear that the
metal, when alone, has not power enough, under the circumstances, to take
the oxygen and expel the hydrogen from the water; for, in fact, no such
action takes place. But it would also appear that it has power so far to
act, by its attraction for the oxygen of the particles in contact with it,
as to place the similar forces already active between these and the other
particles of oxygen and the particles of hydrogen in the water, in a
peculiar state of tension or polarity, and probably also at the same time
to throw those of its own particles which are in contact with the water
into a similar but opposed state. Whilst this state is retained, no further
change occurs; but when it is relieved, by completion of the circuit, in
which case the forces determined in opposite directions, with respect to
the zinc and the electrolyte, are found exactly competent to neutralize
each other, then a series of decompositions and recompositions takes place
amongst the particles of oxygen and hydrogen constituting the water,
between the place of contact with the platina and the place where the zinc
is active; these intervening particles being evidently in close dependence
upon and relation to each other. The zinc forms a direct compound with
those particles of oxygen which were, previously, in divided relation to
both it and the hydrogen: the oxide is removed by the acid, and a fresh
surface of zinc is presented to the water, to renew and repeat the action.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account