Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
950. Practically, the state of tension is best relieved by dipping a metal
which has less attraction for oxygen than the zinc, into the dilute acid,
and making it also touch the zinc. The force of chemical affinity, which
has been influenced or polarized in the particles of the water by the
dominant attraction of the zinc for the oxygen, is then transferred, in a
most extraordinary manner, through the two metals, so as to re-enter upon
the circuit in the electrolytic conductor, which, unlike the metals in that
respect, cannot convey or transfer it without suffering decomposition; or
rather, probably, it is exactly balanced and neutralized by the force which
at the same moment completes the combination of the zinc with the oxygen of
the water. The forces, in fact, of the two particles which are acting
towards each other, and which are therefore in opposite directions, are the
origin of the two opposite forces, or directions of force, in the current.
They are of necessity equivalent to each other. Being transferred forward
in contrary directions, they produce what is called the voltaic current:
and it seems to me impossible to resist the idea that it must be preceded
by a _state of tension_ in the fluid, and between the fluid and the zinc;
the _first consequence_ of the affinity of the zinc for the oxygen of the
water.
951. I have sought carefully for indications of a state of tension in the
electrolytic conductor; and conceiving that it might produce something like
structure, either before or during its discharge, I endeavoured to make
this evident by polarized light. A glass cell, seven inches long, one inch
and a half wide, and six inches deep, had two sets of platina electrodes
adapted to it, one set for the ends, and the other for the sides. Those for
the _sides_ were seven inches long by three inches high, and when in the
cell were separated by a little frame of wood covered with calico; so that
when made active by connexion with a battery upon any solution in the cell,
the bubbles of gas rising from them did not obscure the central parts of
the liquid.
952. A saturated solution of sulphate of soda was put into the cell, and
the electrodes connected with a battery of 150 pairs of 4-inch plates: the
current of electricity was conducted across the cell so freely, that the
discharge was as good as if a wire had been used. A ray of polarized light
was then transmitted through this solution, directly across the course of
the electric current, and examined by an analysing plate; but though it
penetrated seven inches of solution thus subject to the action of the
electricity, and though contact was sometimes made, sometimes broken, and
occasionally reversed during the observations, not the slightest trace of
action on the ray could be perceived.
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