Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
953. The large electrodes were then removed, and others introduced which
fitted the _ends_ of the cell. In each a slit was cut, so as to allow the
light to pass. The course of the polarized ray was now parallel to the
current, or in the direction of its axis (517.); but still no effect, under
any circumstances of contact or disunion, could be perceived upon it.
954. A strong solution of nitrate of lead was employed instead of the
sulphate of soda, but no effects could be detected.
955. Thinking it possible that the discharge of the electric forces by the
successive decompositions and recompositions of the particles of the
electrolyte might neutralize and therefore destroy any effect which the
first state of tension could by possibility produce, I took a substance
which, being an excellent electrolyte when fluid, was a perfect insulator
when solid, namely, borate of lead, in the form of a glass plate, and
connecting the sides and the edges of this mass with the metallic plates,
sometimes in contact with the poles of a voltaic battery, and sometimes
even with the electric machine, for the advantage of the much higher
intensity then obtained, I passed a polarized ray across it in various
directions, as before, but could not obtain the slightest appearance of
action upon the light. Hence I conclude, that notwithstanding the new and
extraordinary state which must be assumed by an electrolyte, either during
decomposition (when a most enormous quantity of electricity must be
traversing it), or in the state of tension which is assumed as preceding
decomposition, and which might be supposed to be retained in the solid form
of the electrolyte, still it has no power of affecting a polarized ray of
light; for no kind of structure or tension can in this way be rendered
evident.
956. There is, however, one beautiful experimental proof of a state of
tension acquired by the metals and the electrolyte before the electric
current is produced, and _before contact_ of the different metals is made
(915.); in fact, at that moment when chemical forces only are efficient as
a cause of action. I took a voltaic apparatus, consisting of a single pair
of large plates, namely, a cylinder of amalgamated zinc, and a double
cylinder of copper. These were put into a jar containing dilute sulphuric
acid[A], and could at pleasure be placed in metallic communication by a
copper wire adjusted so as to dip at the extremities into two cups of
mercury connected with the two plates.
[A] When nitro-sulphuric acid is used, the spark is more powerful, but
local chemical action can then commence, and proceed without requiring
metallic contact.
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