Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
312. A much more convenient and effectual arrangement for chemical
decompositions by common electricity, is the following. Upon a glass plate,
fig. 43, placed over, but raised above a piece of white paper, so that
shadows may not interfere, put two pieces of tinfoil _a, b_; connect one of
these by an insulated wire _c_, or wire and string (301.) with the machine,
and the other _g_, with the discharging train (292.) or the negative
conductor; provide two pieces of fine platina wire, bent as in fig. 44, so
that the part _d, f_ shall be nearly upright, whilst the whole is resting
on the three bearing points _p, e, f_ place these as in fig. 43; the points
_p, n_ then become the decomposing poles. In this way surfaces of contact,
as minute as possible, can be obtained at pleasure, and the connexion can
be broken or renewed in a moment, and the substances acted upon examined
with the utmost facility.
313. A coarse line was made on the glass with solution of sulphate of
copper, and the terminations _p_ and _n_ put into it; the foil _a_ was
connected with the positive conductor of the machine by wire and wet
string, so that no sparks passed: twenty turns of the machine caused the
precipitation of so much copper on the end _n_, that it looked like copper
wire; no apparent change took place at _p_.
314. A mixture of equal parts of muriatic acid and water was rendered deep
blue by sulphate of indigo, and a large drop put on the glass, fig. 43, so
that _p_ and _n_ were immersed at opposite sides: a single turn of the
machine showed bleaching effects round _p_, from evolved chlorine. After
twenty revolutions no effect of the kind was visible at _n_, but so much
chlorine had been set free at _p_, that when the drop was stirred the whole
became colourless.
315. A drop of solution of iodide of potassium mingled with starch was put
into the same position at _p_ and _n_; on turning the machine, iodine was
evolved at _p_, but not at _n_.
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