Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
316. A still further improvement in this form of apparatus consists in
wetting a piece of filtering paper in the solution to be experimented on,
and placing that under the points _p_ and _n_, on the glass: the paper
retains the substance evolved at the point of evolution, by its whiteness
renders any change of colour visible, and allows of the point of contact
between it and the decomposing wires being contracted to the utmost degree.
A piece of paper moistened in the solution of iodide of potassium and
starch, or of the iodide alone, with certain precautions (322.), is a most
admirable test of electro-chemical action; and when thus placed and acted
upon by the electric current, will show iodine evolved at _p_ by only half
a turn of the machine. With these adjustments and the use of iodide of
potassium on paper, chemical action is sometimes a more delicate test of
electrical currents than the galvanometer (273.). Such cases occur when the
bodies traversed by the current are bad conductors, or when the quantity of
electricity evolved or transmitted in a given time is very small.
317. A piece of litmus paper moistened in solution of common salt or
sulphate of soda, was quickly reddened at _p_. A similar piece moistened in
muriatic acid was very soon bleached at _p_. No effects of a similar kind
took place at _n_.
318. A piece of turmeric paper moistened in solution of sulphate of soda
was reddened at _n_ by two or three turns of the machine, and in twenty or
thirty turns plenty of alkali was there evolved. On turning the paper
round, so that the spot came under _p_, and then working the machine, the
alkali soon disappeared, the place became yellow, and a brown alkaline spot
appeared in the new part under _n_.
319. On combining a piece of litmus with a piece of turmeric paper, wetting
both with solution of sulphate of soda, and putting the paper on the glass,
so that _p_ was on the litmus and _n_ on the turmeric, a very few turns of
the machine sufficed to show the evolution of acid at the former and alkali
at the latter, exactly in the manner effected by a volta-electric current.
320. All these decompositions took place equally well, whether the
electricity passed from the machine to the foil _a_, through water, or
through wire only; by _contact_ with the conductor, or by _sparks_ there;
provided the sparks were not so large as to cause the electricity to pass
in sparks from _p_ to _n_, or towards _n_; and I have seen no reason to
believe that in cases of true electro-chemical decomposition by the
machine, the electricity passed in sparks from the conductor, or at any
part of the current, is able to do more, because of its tension, than that
which is made to pass merely as a regular current.
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