Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
321. Finally, the experiment was extended into the following form,
supplying in this case the tidiest analogy between common and voltaic
electricity. Three compound pieces of litmus and turmeric paper (319.) were
moistened in solution of sulphate of soda, and arranged on a plate of glass
with platina wires, as in fig. 45. The wire _m_ was connected with the
prime conductor of the machine, the wire _t_ with the discharging train,
and the wires _r_ and _s_ entered into the course of the electrical current
by means of the pieces of moistened paper; they were so bent as to rest
each on three points, _n, r, p; n, s, p_, the points _r_ and _s_ being
supported by the glass, and the others by the papers; the three
terminations _p, p, p_ rested on the litmus, and the other three _n, n, n_
on the turmeric paper. On working the machine for a short time only, acid
was evolved at _all_ the poles or terminations _p, p, p_, by which the
electricity entered the solution, and alkali at the other poles _n, n, n_,
by which the electricity left the solution.
322. In all experiments of electro-chemical decomposition by the common
machine and moistened papers (316.), it is necessary to be aware of and to
avoid the following important source of error. If a spark passes over
moistened litmus and turmeric paper, the litmus paper (provided it be
delicate and not too alkaline,) is reddened by it; and if several sparks
are passed, it becomes powerfully reddened. If the electricity pass a
little way from the wire over the surface of the moistened paper, before it
finds mass and moisture enough to conduct it, then the reddening extends as
far as the ramifications. If similar ramifications occur at the termination
_n_, on the turmeric paper, they _prevent_ the occurrence of the red spot
due to the alkali, which would otherwise collect there: sparks or
ramifications from the points _n_ will also redden litmus paper. If paper
moistened by a solution of iodide of potassium (which is an admirably
delicate test of electro-chemical action,) be exposed to the sparks or
ramifications, or even a feeble stream of electricity through the air from
either the point _p_ or _n_, iodine will be immediately evolved.
323. These effects must not be confounded with those due to the true
electro-chemical powers of common electricity, and must be carefully
avoided when the latter are to be observed. No sparks should be passed,
therefore, in any part of the current, nor any increase of intensity
allowed, by which the electricity may be induced to pass between the
platina wires and the moistened papers, otherwise than by conduction; for
if it burst through the air, the effect referred to above (322.) ensues.
Public-domain text, read in full here on John Shaqi.
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