Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
With a view to discover where the power of nitrous air to diminish
common air lay, I evaporated to dryness a quantity of the solution of
copper in diluted spirit of nitre; and having procured from it a
quantity of a _green precipitate_, I threw the focus of a burning-glass
upon it, when it was put into a vessel of quicksilver, standing inverted
in a bason of quicksilver. In this manner I procured air from it, which
appeared to be, in all respects, nitrous air; so that part of the same
principle which had escaped during the solution, in the form of _air_,
had likewise been retained in it, and had not left it in the evaporation
of the water.
With great difficulty I also procured a small quantity of the same kind
of air from a solution of _iron_ in spirit of nitre, by the same
process.
Having, for a different purpose, fired some paper, which had been dipped
in a solution of copper in diluted spirit of nitre, in nitrous air, I
found there was a considerable addition to the quantity of it; upon
which I fired some of the same kind of paper in quicksilver and
presently observed that air was produced from it in great plenty. This
air, at the first, seemed to have some singular properties, but
afterwards I found that it was nothing more than a mixture of nitrous
air, from the precipitate of the solution, and of inflammable air, from
the paper; but that the former was predominant.
In the mixture of this kind of air with common air, in a trough of water
which had been putrid, but which at that time seemed to have recovered
its former sweetness (for it was not in the least degree offensive to
the smell) a phenomenon sometimes occurred, which for a long time
exceedingly delighted and puzzled me; but which was afterwards the means
of letting me see much farther into the constitution of nitrous air than
I had been able to see before.
When the diminution of the air was nearly completed, the vessel in which
the mixture was made began to be filled with the most beautiful _white
fumes_, exactly resembling the precipitation of some white substance in
a transparent menstruum, or the falling of very fine snow; except that
it was much thicker below than above, as indeed is the case in all
chemical precipitations. This appearance continued two or three minutes.
Public-domain text, read in full here on John Shaqi.
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