Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
At other times I went over the same process, as nearly as possible in
the same manner, but without getting this remarkable appearance, and was
several times greatly disappointed and chagrined, when I baulked the
expectations of my friends, to whom I had described, and meant to have
shewn it. This made me give all the attention I possibly could to this
experiment, endeavouring to recollect every circumstance, which, though
unsuspected at the time, might have contributed to produce this new
appearance; and I took a great deal of pains to procure a quantity of
this air from the paper above mentioned for the purpose, which, with a
small burning lens, and an uncertain sun, is not a little troublesome.
But all that I observed for some time was, that I stood the best chance
of succeeding when I _warmed_ the vessel in which the mixture was made,
and _agitated_ the air during the effervescence.
Finding, at length, that, with the same preparation and attentions, I
got the same appearance from a mixture of nitrous and common air in the
same trough of water, I concluded that it could not depend upon any
thing peculiar to the precipitate of the _copper_ contained in the
_paper_ from which the air was procured, as I had at first imagined, but
upon what was common to it, and pure nitrous air.
Afterwards, having, (with a view to observe whether any crystals would
be formed by the union of volatile alkali, and nitrous air, similar to
those formed by it and fixed air, as described by Mr. Smeth in his
_Dissertation on fixed Air_) opened the mouth of a phial which was half
filled with a volatile alkaline liquor, in a jar of nitrous air (in the
manner described p. 11. fig. 4.) I had an appearance which perfectly
explained the preceding. All that part of the phial which was above the
liquor, and which contained common air, was filled with beautiful
_white clouds_, as if some fine white powder had been instantly thrown
into it, and some of these clouds rose within the jar of nitrous air.
This appearance continued about a minute, and then intirely disappeared,
the air becoming transparent.
Withdrawing the phial, and exposing it to the common air, it there also
became turbid, and soon after the transparency returned. Introducing it
again into the nitrous air, the clouds appeared as before. In this
manner the white fumes, and transparency, succeeded each other
alternately, as often as I chose to repeat the experiment, and would no
doubt have continued till the air in the jar had been thoroughly diluted
with common air. These appearances were the same with any substance that
contained _volatile alkali_, fluid or solid.
Public-domain text, read in full here on John Shaqi.
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