Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
When, instead of the small phial, I used a large and tall glass jar,
this appearance was truly fine and striking, especially when the water
in the trough was very transparent. For I had only to put the smallest
drop of a volatile alkaline liquor, or the smallest bit of the solid
salt, into the jar, and the moment that the mouth of it was opened in a
jar of nitrous air, the white clouds above mentioned began to be formed
at the mouth, and presently descended to the bottom, so as to fill the
whole, were it ever so large, as with fine snow.
In considering this experiment, I soon perceived that this curious
appearance must have been occasioned by the mixture of the nitrous and
common air, and therefore that the white clouds must be _nitrous
ammoniac_, formed by the acid of the nitrous air, set loose in the
decomposition of it by common air, while the phlogiston, which must be
another constituent part of nitrous air, entering the common air, is the
cause of the diminution it suffers in this process; as it is the cause
of a similar diminution, in a variety of other processes.
I would observe, that it is not peculiar to nitrous air to be a test of
the fitness of air for respiration. Any other process by which air is
diminished and made noxious answers the same purpose. Liver of sulphur
for instance, the calcination of metals, or a mixture of iron filings
and brimstone will do just the same thing; but the application of them
is not so easy, or elegant, and the effect is not so soon perceived. In
fact, it is _phlogiston_ that is the test. If the air be so loaded with
this principle that it can take no more, which is seen by its not being
diminished in any of the processes above mentioned, it is noxious; and
it is wholesome in proportion to the quantity of phlogiston that it is
able to take.
This, I have no doubt, is the true theory of the diminution of common
air by nitrous air, the redness of the appearance being nothing more
than the usual colour of the fumes, of spirit of nitre, which is now
disengaged from the superabundant phlogiston with which it was combined
in the nitrous air, and ready to form another union with any thing that
is at hand, and capable of it.
With the volatile alkali it forms nitrous ammoniac, water imbibes it
like any other acid, even quicksilver is corroded by it; but this action
being slow, the redness in this mixture of nitrous and common air
continues much longer when the process is made in quicksilver, than when
it is made in water, and the diminution, as I have also observed; is by
no means so great.
Public-domain text, read in full here on John Shaqi.
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