Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
In the method in which I generally made the fixed air (and indeed
always, unless the contrary be particularly mentioned, viz. by diluted
oil of vitriol and chalk) I found by experiment that it was as pure as
Mr. Cavendish made it. For after it had patted through a large body of
water in small bubbles, still 1/50 or 1/60 part only was not absorbed by
water. In order to try this as expeditiously as possible, I kept pouring
the air from one glass vessel into another, immersed in a quantity of
cold water, in which manner I found by experience, that almost any
quantity may be reduced as far as possible in a very short time. But the
most expeditious method of making water imbibe any kind of air, is to
confine it in a jar; and agitate it strongly, in the manner described in
my pamphlet on the impregnation of water with fixed air, and represented
fig. 10.
At the same time that I was trying the purity of my fixed air, I had the
curiosity to endeavour to ascertain whether that part of it which is not
miscible in water, be equally diffused through the whole mass; and, for
this purpose, I divided a quantity of about a gallon into three parts,
the first consisting of that which was uppermost, and the last of that
which was the lowest, contiguous to the water; but all these parts were
reduced in about an equal proportion, by passing through the water, so
that the whole mass had been of an uniform composition. This I have also
found to be the case with several kinds of air, which will, not properly
incorporate.
A mouse will live very well, though a candle will not burn in the
residuum of the purest fixed air that I can make; and I once made a very
large quantity for the sole purpose of this experiment. This, therefore,
seems to be one instance of the generation of genuine common air, though
vitiated in some degree. It is also another proof of the residuum of
fixed air being, in part at least, common air, that it becomes turbid,
and is diminished by the mixture of nitrous air, as will be explained
hereafter.
That fixed air only wants some addition to make it permanent, and
immiscible with water if not in all respects, common air, I have been
led to conclude, from several attempts which I once made to mix it with
air in which a quantity of iron filings and brimstone, made into a paste
with water, had stood; for, in several mixtures of this kind, I imagined
that not much more than half of the fixed air could be imbibed by water;
but, not being able to repeat the experiment, I conclude that I either
deceived myself in it, or that I overlooked some circumstance on which
the success of it depended.
Public-domain text, read in full here on John Shaqi.
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