Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
It is well known that flame cannot subsist long without change of air,
so that the common air is necessary to it, except in the case of
substances, into the composition of which nitre enters, for these will
burn _in vacuo_, in fixed air, and even under water, as is evident in
some rockets, which are made for this purpose. The quantity of air which
even a small flame requires to keep it burning is prodigious. It is
generally said, that an ordinary candle _consumes_, as it is called,
about a gallon in a minute. Considering this amazing consumption of air,
by fires of all kinds, volcanos, &c. it becomes a great object of
philosophical inquiry, to ascertain what change is made in the
constitution of the air by flame, and to discover what provision there
is in nature for remedying the injury which the atmosphere receives by
this means. Some of the following experiments will, perhaps, be thought
to throw light upon the subject.
The diminution of the quantity of air in which a candle, or brimstone,
has burned out, is various; But I imagine that, at a medium, it may be
about one fifteenth, or one sixteenth of the whole; which is one third
as much as by animal or vegetable substances putrefying in it, by the
calcination of metals, or by any of the other causes of the complete
diminution of air, which will be mentioned hereafter.
I have sometimes thought, that flame disposes the common air to deposit
the fixed air it contains; for if any lime-water be exposed to it, it
immediately becomes turbid. This is the case, when wax candles, tallow
candles, chips of wood, spirit of wine, ether, and every other substance
which I have yet tried, except brimstone, is burned in a close glass
vessel, standing in lime-water. This precipitation of fixed air (if this
be the case) may be owing to something emitted from the burning bodies,
which has a stronger affinity with the other constituent parts of the
atmosphere[3].
If brimstone be burned in the same circumstances, the lime-water
continues transparent, but still there may have been the same
precipitation of the fixed part of the air; but that, uniting with the
lime and the vitriolic acid, it forms a selenetic salt, which is soluble
in water. Having evaporated a quantity of water thus impregnated, by
burning brimstone a great number of times over it, a whitish powder
remained, which had an acid taste; but repeating the experiment with a
quicker evaporation, the powder had no acidity, but was very much like
chalk. The burning of brimstone but once over a quantity of lime-water,
will affect it in such a manner, that breathing into it will not make it
turbid, which otherwise it always presently does.
Public-domain text, read in full here on John Shaqi.
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