Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
The effect of this process is generally perceived in five or six hours,
about which time the visible effervesence of the mixture begins; and in
a very short time it advances so rapidly, that in about an hour almost
the whole effect will have taken place. If it be suffered to stand a day
or two longer, the air will still be diminished farther, but only a very
little farther, in proportion to the first diminution. The glass jar,
in which the air and this mixture have been confined, has generally been
so much heated in this process, that I have not been able to touch it.
Nitrous air thus diminished has not so strong a smell as nitrous air
itself, but smells just like common air in which the same mixture has
stood; and it is not capable of being diminished any farther, by a fresh
mixture of iron and brimstone.
Common air saturated with nitrous air is also no farther diminished by
this mixture of iron filings and brimstone, though the mixture ferments
with great heat, and swells very much in it.
Plants die very soon, both in nitrous air, and also in common air
saturated with nitrous air, but especially in the former.
Neither nitrous air, nor common air saturated with nitrous air, differ
in specific gravity from common air. At least, the difference is so
small, that I could not be sure there was any; sometimes about three
pints of it seeming to be about half a grain heavier, and at other times
as much lighter than common air.
Having, among other kinds of air, exposed a quantity of nitrous air to
water out of which the air had been well boiled, in the experiment to
which I have more than once referred (as having been the occasion of
several new and important observations) I found that 19/20 of the whole
was absorbed. Perceiving, to my great surprize, that so very great a
proportion of this kind of air was miscible with water, I immediately
began to agitate a considerable quantity of it, in a jar standing in a
trough of the same kind of water; and, with about four times as much
agitation as fixed air requires, it was so far absorbed by the water,
that only about one fifth remained. This remainder extinguished flame,
and was noxious to animals.
Afterwards I diminished a pretty large quantity of nitrous air to one
eighth of its original bulk, and the remainder still retained much of
its peculiar smell, and diminished common air a little. A mouse also
died in it, but not so suddenly as it would have done in pure nitrous
air. In this operation the peculiar smell of nitrous air is very
manifest, the water being first impregnated with the air, and then
transmitting it to the common atmosphere.
Public-domain text, read in full here on John Shaqi.
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