Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
This experiment gave me the hint of impregnating water with nitrous air,
in the manner in which I had before done it with fixed air; and I
presently found that distilled water would imbibe about one tenth of its
bulk of this kind of air, and that it acquired a remarkably acid and
astringent taste from it. The smell of water thus impregnated is at
first peculiarly pungent. I did not chuse to swallow any of it, though,
for any thing that I know, it may be perfectly innocent, and perhaps, in
some cases, salutary.
This kind of air is retained very obstinately by water. In an exhausted
receiver a quantity of water thus saturated emitted a whitish fume, such
as sometimes issues from bubbles of this air when it is first generated,
and also some air-bubbles; but though it was suffered to stand a long
time in this situation, it still retained its peculiar taste; but when
it had stood all night pretty near the fire, the water was become quite
vapid, and had deposited a filmy kind of matter, of which I had often
collected a considerable quantity from the trough in which jars
containing this air had stood. This I suppose to be a precipitate of the
metal, by the solution of which the nitrous air was generated. I have
not given so much attention to it as to know, with certainty, in what
circumstances this _deposit_ is made, any more than I do the matter
deposited from inflammable air above-mentioned; for I cannot get it, at
least in any considerable quantity, when I please; whereas I have often
found abundance of it, when I did not expect it at all.
The nitrous air with which I made the first impregnation of water was
extracted from copper; but when I made the impregnation with air from
quicksilver, the water had the very same taste, though the matter
deposited from it seemed to be of a different kind; for it was whitish,
whereas the other had a yellowish tinge. Except the first quantity of
this impregnated water, I could never deprive any more that I made of
its peculiar taste. I have even let some of it stand more than a week,
in phials with their mouths open, and sometimes very near the fire,
without producing any alteration in it[6].
Whether any of the spirit of nitre contained in the nitrous air be mixed
with the water in this operation, I have not yet endeavoured to
determine. This, however, may probably be the case, as the spirit of
nitre is, in a considerable degree, volatile[7].
Public-domain text, read in full here on John Shaqi.
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