Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
Wanting, however, to procure this air in greater quantities, and this
method being rather expensive, it occurred to me, that alkaline air
might, probably, be procured, with the most ease and convenience, from
the original materials, mixed in the same proportions that chemists had
found by experience to answer the best for the production of the
volatile spirit of sal ammoniac. Accordingly I mixed one fourth of
pounded sal ammoniac, with three fourths of slaked lime; and filling a
phial with the mixture, I presently found it completely answered my
purpose. The heat of a candle expelled from this mixture a prodigious
quantity of alkaline air; and the same materials (as much as filled an
ounce phial) would serve me a considerable time, without changing;
especially when, instead of a glass phial, I made use of a small iron
tube, which I find much more convenient for the purpose.
As water soon begins to rise in this process, it is necessary, if the
air is intended to be conveyed perfectly _dry_ into the vessel of
quicksilver, to have a small vessel in which this water (which is the
common volatile spirit of sal ammoniac) may be received. This small
vessel must be interposed between the vessel which contains the
materials for the generation of the air, and that in which it is to be
received, as _d_ fig. 8.
This _alkaline_ air being perfectly analogous to the _acid_ air, I was
naturally led to investigate the properties of it in the same manner,
and nearly in the same order. From this analogy I concluded, as I
presently found to be the fact, that this alkaline air would be readily
imbibed by water, and, by its union with it, would form a volatile
spirit of sal ammoniac. And as the water, when admitted to the air in
this manner, confined by quicksilver, has an opportunity of fully
saturating itself with the alkaline vapour, it is made prodigiously
stronger than any volatile spirit of sal ammoniac that I have ever seen;
and I believe stronger than it can be made in the common way.
In order to ascertain what addition, with respect to quantity and
weight, water would acquire by being saturated with alkaline air, I put
1-1/4 grains of rain-water into a small glass tube, closed at one end
with cement, and open at the other, the column of water measuring 7/10
of an inch; and having introduced it through the quicksilver into a
vessel containing alkaline air, observed that it absorbed 7/8 of an
ounce measure of the _air_, and had then gained about half a grain in
weight, and was increased to 8-1/2 tenths of an inch in length. I did
not make a second experiment of this kind, and therefore will not answer
for the exactness of these proportions in future trials. What I did
sufficiently answered my purpose, in a general view of the subject.
Public-domain text, read in full here on John Shaqi.
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