Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
When I had, at one time, saturated a quantity of distilled water with
alkaline air, so that a good deal of the air remained unabsorbed on the
surface of the water, I observed that, as I continued to throw up more
air, a considerable proportion of it was imbibed, but not the whole; and
when I had let the apparatus stand a day, much more of the air that lay
on the surface was imbibed. And after the water would imbibe no more of
the _old_ air, it imbibed _new_. This shews that water requires a
considerable time to saturate itself with this kind of air, and that
part of it more readily unites with water than the rest.
The same is also, probably, the case with all the kinds of air with
which water can be impregnated. Mr. Cavendish made this observation with
respect to fixed air, and I repeated the whole process above-mentioned
with acid air, and had precisely the same result. The alkaline water
which I procured in this experiment was, beyond comparison, stronger to
the smell, than any spirit of sal ammoniac that I had seen.
This experiment led me to attempt the making of spirit of sal ammoniac
in a larger quantity, by impregnating distilled water with this alkaline
air. For this purpose I filled a piece of a gun-barrel with the
materials above-mentioned, and luted to the open end of it a small glass
tube, one end of which was bent, and put within the mouth of a glass
vessel, containing a quantity of distilled water upon quicksilver,
standing in a bason of quicksilver, as in fig. 7. In these circumstances
the heat of the fire, applied gradually, expelled the alkaline air,
which, passing through the tube, and the quicksilver, came at last to
the water, which, in time, became fully saturated with it.
By this means I got a very strong alkaline liquor, from which I could
again expel the alkaline air which I had put into it, whenever it
happened to be more convenient to me to get it in that manner. This
process may easily be performed in a still larger way; and by this means
a liquor of the same nature with the volatile spirit of sal ammoniac,
might be made much stronger, and much cheaper, than it is now made.
Having satisfied myself with respect to the relation that alkaline air
bears to water, I was impatient to find what would be the consequence
of mixing this new air with the other kinds with which I was acquainted
before, and especially with _acid_ air; having a notion that these two
airs, being of opposite natures, might compose a _neutral air_, and
perhaps the very same thing with common air. But the moment that these
two kinds of air came into contact, a beautiful white cloud was formed,
and presently filled the whole vessel in which they were contained. At
the same time the quantity of air began to diminish, and, at length,
when the cloud was subsided, there appeared to be formed a solid _while
salt_, which was found to be the common _sal ammoniac_, or the marine
acid united to the volatile alkali.
Public-domain text, read in full here on John Shaqi.
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