Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
The first quantity that I produced immediately deliquesced, upon being
exposed to the common air; but if it was exposed in a very dry and warm
place, it almost all evaporated, in a white cloud. I have, however,
since, from the same materials, produced the salt above-mentioned in a
state not subject to deliquesce or evaporate. This difference, I find,
is owing to the proportion of the two kinds of air in the compound. It
is only volatile when there is more than a due proportion of either of
the constituent parts. In these cases the smell of the salts is
extremely pungent, but very different from one another; being manifestly
acid, or alkaline, according to the prevalence of each of these airs
respectively.
_Nitrous air_ admitted to alkaline air likewise occasioned a whitish
cloud, and part of the air was absorbed; but it presently grew clear
again; leaving only a little dimness on the sides of the vessel. This,
however, might be a kind of salt, formed by the union of the two kinds
of air. There was no other salt formed that I could perceive. Water
being admitted to this mixture of nitrous and alkaline air presently
absorbed the latter, and left the former possessed of its peculiar
properties.
_Fixed air_ admitted to alkaline air formed oblong and slender crystals,
which crossed one another, and covered the sides of the vessel in the
form of net-work. These crystals must be the same thing with the
volatile alkalis which chemists get in a solid form, by the distillation
of sal ammoniac with fixed alkaline salts.
_Inflammable air_ admitted to alkaline air exhibited no particular
appearance. Water, as in the former experiment, absorbed the alkaline
air, and left the inflammable air as it was before. It was remarkable,
however, that the water which was admitted to them became whitish, and
that this white cloud settled, in the form of a white powder, to the
bottom of the vessel.
Alkaline air mixed with _common air_, and standing together several
days, first in quicksilver, and then in water (which absorbed the
alkaline air) it did not appear that there was any change produced in
the common air: at least it was as much diminished by nitrous air as
before. The same was the case with a mixture of acid air and common air.
Having mixed air that had been diminished by the fermentation of a
mixture of iron filings and brimstone with alkaline air, the water
absorbed the latter, but left the former, with respect to the test of
nitrous air (and therefore, as I conclude, with respect to all its
properties) the same that it was before.
_Spirit of wine_ imbibes alkaline air as readily as water, and seems to
be as inflammable afterwards as before.
Alkaline air contracts no union with _olive oil_. They were in contact
almost two days, without any diminution of the air. Oil of turpentine,
and essential oil of mint, absorbed a very small quantity of alkaline
air, but were not sensibly changed by it.
Public-domain text, read in full here on John Shaqi.
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