Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
Twenty six ounces of very strong quick-lime made of chalk, were slaked
or reduced to a sort of fluid paste, with eleven pounds of boiling
water, and then mixed in a glass vessel with eighteen ounces of a pure
fixed alkaline salt, which had been first dissolved in two pounds and a
half of water. This mixture was shaken frequently for two hours, when
the action of the lime upon the alkali was supposed to be over, and
nothing remained but to separate them again from one another. I
therefore added 12 pounds of water, stirred up the lime, and, after
allowing it to settle again, poured off as much of the clear ley as
possible.
The lime and alkali were mixed together under the form of a very thick
milky liquor or fluid paste; because they are thus kept in perpetual
contact and equal mixture until they have acted sufficiently upon one
another: whereas in the common way of using a larger quantity of water,
the lime lies for the most part at bottom, and, tho' stirred up ever so
often, cannot exert its influence so fully upon the alkali, which is
uniformly diffused thro' every part of the liquor.
The above ley was found upon trial to be saturated by acids without the
least effervescence or diminution of weight.
It was now proper to examine whether the alkali suffered any loss in
becoming caustic, which I proposed to attempt by ascertaining the
strength of the ley, or the quantity of salt which a given portion of it
contained; from which by computation some imperfect knowledge might be
obtained of the quantity of caustic produced from the eighteen ounces of
mild salt.
I therefore evaporated some of my ley, but soon perceived that no
certain judgment could be formed of its strength in this way, because it
always absorbed a considerable quantity of air during the evaporation,
and the dried salt made a pretty brisk effervescence with acids, so that
the ley appeared stronger than it really was; and yet, upon proceeding
in the estimate from this rude and unfair trial, it appeared that the
salt had lost above a sixth in becoming caustic, and the quantity of
acid saturated by two drams of it was to the quantity of acid saturated
by two drams of salt of tartar, nearly as six to five.
These experiments are therefore agreeable to that part of the second
proposition which relates to the caustic alkali.
Public-domain text, read in full here on John Shaqi.
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