Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances — John Shaqi
Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
As it seems probable, from the quickness and ease wherewith the alkali
was rendered caustic, that more lime had been employed than what was
just sufficient to extract the whole of its air, we are surprised to
find that little or none of the superfluous quick-lime was dissolved by
the water. But this _phaenomenon_ will become less surprizing, by
comparing it with some similar instances in chemistry. Water may be made
to deposite a salt, by the admixture of a substance which it attracts
more strongly than it does that salt; such as spirit of wine; and
quick-lime itself may be separated from water upon the same principle;
for if that spirit is added to an equal quantity of lime-water, the
mixture becomes turbid and deposites a sediment, which, when separated
and dissolved again in distilled water, composes lime-water. We may
therefore refer the above _phaenomenon_, with respect to the ley, to the
same cause with these, and say, that the water did not dissolve the
lime, because it already contained a caustic alkali, for which it has a
superior attraction.
I also rendered the volatile alkali caustic, in order to examine what
change it suffered in the operation, and obtained an exceedingly
volatile and acrid spirit, which neither effervesced with acids, nor
altered in the least the transparency of lime-water; and, altho' very
strong, was lighter than water, and floated upon it like spirit of wine.
I next inquired into the truth of the fifth proposition, in the
following manner.
Two drams of epsom-salt were dissolved in a small quantity of water, and
thrown into two ounces of the caustic-ley; the mixture instantly became
thick, like a decoction of starch or barley, by the magnesia, which was
precipitated. I then added spirit of vitriol by degrees, until the
mixture became perfectly clear, or the whole of the magnesia was again
dissolved; which happened without any effervescence or emission of air.
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