Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
The above-mentioned Author observing, some time after, that a bitter
saline liquor, similar to that obtained from the brine of salt-petre,
was likewise produced by the evaporation of those waters which contain
common salt, had the curiosity to try if this would also yield a
_magnesia_. The experiment succeeded: and he thus found out another
process for obtaining this powder, and at the same time assured himself
by experiments, that the product from both was exactly the same.[3]
My curiosity led me some time ago to inquire more particularly into the
nature of _magnesia_, and especially to compare its properties with
those of the other absorbent earths, of which there plainly appeared to
me to be very different kinds, altho' commonly confounded together under
one name. I was indeed led to this examination of the absorbent earths,
partly by the hope of discovering a new sort of lime and lime-water,
which might possibly be a more powerful solvent of the stone than that
commonly used; but was disappointed in my expectations.
I have had no opportunity of seeing _Hoffman's_ first _magnesia_ or the
liquor from which it is prepared, and have therefore been obliged to
make my experiments upon the second.
In order to prepare it, I at first employed the bitter saline liquor
called _bittern_, which remains in the pans after the evaporation of sea
water. But as that liquor is not always easily procured, I afterwards
made use of a salt called _epsom-salt_, which is separated from the
bittern by crystallization, and is evidently composed of _magnesia_ and
the vitriolic acid.
There is likewise a spurious kind of Glauber salt, which yields plenty
of _magnesia_, and seems to be no other than the epsom salt of sea water
reduced to crystals of a larger size. And common salt also affords a
small quantity of this powder; because being separated from the bittern
by one hasty crystallization only, it necessarily contains a portion of
that liquor.
Those who would prepare a _magnesia_ from epsom-salt, may use the
following process.
Dissolve equal quantities of epsom-salt, and of pearl ashes separately
in a sufficient quantity of water; purify each solution from its dregs,
and mix them accurately together by violent agitation: then make them
just to boil over a brisk fire.
Add now to the mixture three or four times its quantity of hot water;
after a little agitation, allow the _magnesia_ to settle to the bottom,
and decant off as much of the water as possible. Pour on the same
quantity of cold water; and, after settling, decant it off in the same
manner. Repeat this washing with the cold water ten or twelve times: or
even oftner, if the _magnesia_ be required perfectly pure for chemical
experiments.
When it is sufficiently washed, the water may be strained and squeezed
from it in a linen cloth; for very little of the _magnesia_ passes
thro'.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account